Citation: Li-Zhuang Chen, Deng-Deng Huang, Qi-Jian Pan, Fang-Ming Wang. Ferroelectricity based on coordination compound：Transition metal Co(II) sulfates templated by homochiral 2-methylpiperazine (C₅H₁₄N₂)[Co(H₂O)₆](SO₄)₂[J]. Chinese Chemical Letters, ;2014, 25(6): 967-971. doi: 10.1016/j.cclet.2014.05.038 shu

Ferroelectricity based on coordination compound：Transition metal Co(II) sulfates templated by homochiral 2-methylpiperazine (C₅H₁₄N₂)[Co(H₂O)₆](SO₄)₂

1.
a School of Biology and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
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b State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: Li-Zhuang Chen,
Received Date: 17 February 2014
Available Online: 22 April 2014
Fund Project: This work was funded by the National Natural Science Foundation of China (No. 21201087) (No. 21201087)sponsored by Qing Lan Project of Jiangsu province. L.-Z. Chen thanks Prof. Xiong Ren-Gen for revising this manuscript. Sponsored by Qing Lan Project of Jiangsu Province and Jiangsu Overseas Research & Training Program for University Prominent Young & Middle-aged Teacher and Presidents. (No. 11KJB150004)

Reacting homochiral (R)-2-methylpiperazine with cobalt sulfate heptahydrate by the solution method in the presence of concentrated sulfuric acid (H₂SO₄) yielded two coordination compounds (C₅H₁₄N₂) [Co(H₂O)₆](SO₄)₂ (1 and 2). They are polymorphs, but their hydrogen bonds structure differ significantly. Both 1 and 2 crystallize in chiral space group P2₁ which is related with point group C₂, and experimental results suggest that 1 displays ferroelectric behaviors.
- Co(II) compound,
- Homochiral,
- Ferroelectric,
- Dielectric
1. [1]
  [1] (a) W. Zhang, L.Z. Chen, R.G. Xiong, T. Nakamura, S.P.D. Huang, New ferroelectrics based on divalent metal ion alum, J. Am. Chem. Soc. 131 (2009) 12544-12545;(b) W. Zhang, R.G. Xiong, Ferroelectric metal-organic frameworks, Chem. Rev. 112 (2012) 1163-1195.
2. [2]
  [2] L.Z. Chen, D.D. Huang, J.Z. Ge, F.M. Wang, A novel Ag(I) coordination polymers based on 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic acid: syntheses, structures, ferroelectric, dielectric and optical properties, Inorg. Chim. Acta 406 (2013) 95-99.
3. [3]
  [3] P.A. Maggard, C.L. Stern, K.R. Poeppelmeier, Understanding the role of helical chains in the formation of noncentrosymmetric solids, J. Am. Chem. Soc. 123 (2001) 7742-7743.
4. [4]
  [4] H.L. Cai, T. Zhang, L.Z. Chen, R.G. Xiong, The first homochiral compound with temperature-independence of piezoelectric properties, J. Mater. Chem. 20 (2010) 1868-1870.
5. [5]
  [5] H. Zhang, X.M. Wang, K.C. Zhang, B.K. Teo, Molecular and crystal engineering of a new class of inorganic cadmiuμ-thiocyanate polymers with host-guest complexes as organic spacers, controllers, and templates, Coord, Chem. Rev. 183 (1999) 157-195.
6. [6]
  [6] L.N. Li, J.X. Ma, C. Song, et al., A 3D polar nanotubular coordination polymer with dynamic structural transformation and ferroelectric and nonlinear-optical properties, Inorg. Chem. 51 (2012) 2438-2442.
7. [7]
  [7] W. Eerenstein, N.D. Mathur, J.F. Scott, Multiferroic and magnetoelectric materials, Nature 442 (2006) 759-765.
8. [8]
  [8] D.W. Fu, H.L. Cai, Y.M. Liu, et al., Diisopropylammonium bromide is a hightemperature molecular ferroelectric crystal, Science 339 (2013) 425-428.
9. [9]
  [9] S. Horiuchi, Y. Tokura, Organic ferroelectrics, Nat. Mater. 7 (2008) 357-366.
10. [10]
  [10] J.F. Scott, Applications of modern ferroelectrics, Science 315 (2007) 954-959.
11. [11]
  [11] (a) Y. Zhang, W. Zhang, S.H. Li, et al., Ferroelectricity induced by ordering of twisting motion in a molecular rotor, J. Am. Chem. Soc. 134 (2012) 11044-11049;(b) D.W. Fu, Y.M. Song, G.X. Wang, et al., Dielectric anisotropy of a homochiral trinuclear nickel(II) complex, J. Am. Chem. Soc. 129 (2007) 5346-5347.
12. [12]
  [12] G.C. Xu, X.M. Ma, Z. Li, Z.M. Wang, S. Gao, Disorder-order ferroelectric transition in the metal formate framework of [NH₄][Zn(HCOO)₃], J. Am. Chem. Soc. 132 (2010) 9588-9590.
13. [13]
  [13] H.X. Zhao, X.J. Kong, H. Li, et al., Transition from one-dimensional water to ferroelectric ice within a supramolecular architecture, Proc. Natl. Acad. Sci. U.S.A. 108 (2011) 3481-3486.
14. [14]
  [14] (a) A.N. Holden, B.T. Matthias, W.J. Merz, J.P. Remeika, New class of ferroelectrics, Phys. Rev. 98 (1955) 546;(b) N. Galesic, V.B. Jordanovska, Structures of dimethylammonium metal(III) sulfate hexahydrates (metal=Al, Cr), Acta Crystallogr. Sect. C 48 (1992) 256-258;(c) L.F. Kirpichnikova, L.A. Shuvalov, N.R. Ivanov, B.N. Prasolov, E.F. Andreyev, Ferroelectricity in the dimethylaminaluminiuμ-sulphate crystal, Ferroelectrics 96 (1989) 313-317.
15. [15]
  [15] F. Hajlaoui, H. Naïli, S. Yahyaoui, et al., Synthesis, crystal structures and thermal behaviour of organic-inorganic hybrids incorporating a chiral diamine, J. Organomet. Chem. 700 (2012) 110-116.
16. [16]
  [16] G.M. Sheldrick, SHELXS-97, in: Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
17. [17]
  [17] G.M. Sheldrick, SHELXL-97, in: Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
18. [18]
  [18] T. Zhang, L.Z. Chen, M. Gou, et al., Ferroelectric homochiral organic molecular crystals, Cryst. Growth Des. 10 (2010) 1025-1027.
19. [19]
  [19] (a) Z.H. Sun, T.L. Chen, J.H. Luo, M.C. Hong, Bis(imidazolium) L-tartrate: a hydrogen-bonded displacive-type molecular ferroelectric material, Angew. Chem. Int. Ed. 51 (2012) 3871-3876;(b) D.W. Fu, W. Zhang, H.L. Cai, et al., A multiferroic perdeutero metal-organic framework, Angew. Chem. Int. Ed. 50 (2011) 11947-11951.
20. [20]
  [20] (a) L.Z. Chen, H. Zhao, J.Z. Ge, R.G. Xiong, H.W. Hu, Observation of deuteration effect in Co-crystal system: hexame-thylenetetraminium 3,5-dinitrobenzoate hemideuterated water, Cryst. Growth Des. 9 (2009) 3828-3831;(b) L.Z. Chen, D.D. Huang, J.Z. Ge, F.M. Wang, Temperature-induced reversible structural phase transition of 1-(chloromethyl)-1,4-diazoniabicyclo[2.2.2]octane bis(perchlorate), CrystEngComm 16 (2014) 2944-2949;(c) L.Z. Chen, D.D. Huang, Synthesis, structure and dielectric properties of a novel Gd coordination polymer based on 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate, Chin. Chem. Lett. 25 (2014) 279-282.
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沈阳化工大学材料科学与工程学院沈阳 110142

Ferroelectricity based on coordination compound：Transition metal Co(II) sulfates templated by homochiral 2-methylpiperazine (C5H14N2)[Co(H2O)6](SO4)2

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通讯作者: 陈斌, bchen63@163.com

Ferroelectricity based on coordination compound：Transition metal Co(II) sulfates templated by homochiral 2-methylpiperazine (C₅H₁₄N₂)[Co(H₂O)₆](SO₄)₂