Citation: Xiao-Dong Xia, Tian-Lun Wang, Xiao-Yuan Yuan. Tuning plasmon absorption of unmodified silver nanoplates for sensitive and selective detection of copper ions by introduction of ascorbate[J]. Chinese Chemical Letters, ;2014, 25(10): 1403-1406. doi: 10.1016/j.cclet.2014.05.033 shu

Tuning plasmon absorption of unmodified silver nanoplates for sensitive and selective detection of copper ions by introduction of ascorbate

1.
Key Laboratory of Theoretical Chemistry and Molecular Simulation, Minister of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China

Corresponding author: Xiao-Dong Xia,
Received Date: 24 February 2014
Available Online: 29 April 2014
Fund Project: This work is supported by the National Natural Science Foundation of China (No. 21375036) (No. 21375036)

Silver nanoplates as novel optical sensors for Cu²⁺ detection have been demonstrated. Silver nanoplates are synthesized via previous H₂O₂-NaBH₄ cyclic oxidation-reduction reactions. With introduction of ascorbate as mild reductants, Cu²⁺ ions are reduced into Cu⁺ and the Cu⁺ is further reduced to Cu, which is deposited on the surface of the silver nanoplates. The deposition of the Cu on the surface of the silver nanoplates allows a significant red-shift of their plasmon absorption. Therefore, trace Cu²⁺ can be detected. The shift of the plasmon absorption wavelength of silver nanoplates is proportional to the Cu²⁺ concentration over a range of 40-340 μmol L^-1 with a limit of detection of 9.0 μmol L^-1. Moreover, such silver nanoplate-based optical sensors provide good selectivity for Cu²⁺ detection, and most other metal ions do not disturb its detection. Moreover, the practicality of the proposed sensor was tested. This Cu²⁺ assay is advantageous in its simplicity, selectivity, and cost-effectiveness.
- Silver nanoplate,
- Plasmon absorption,
- Wavelength shift,
- Optical sensor,
- Copper ions,
- Ascorbate
1. [1]
  [1] M. Rycenga, C.M. Cobley, J. Zeng, et al., Controlling the synthesis and assembly of silver nanostructures for plasmonic applications, Chem. Rev. 111 (2011) 3669-3712.
2. [2]
  [2] M.R. Jones, K.D. Osberg, R.J. Macfarlane, M.R. Langille, C.A. Mirkin, Templated techniques for the synthesis and assembly of plasmonic nanostructures, Chem. Rev. 111 (2011) 3736-3827.
3. [3]
  [3] K.M. Mayer, J.H. Hafner, Localized surface plasmon resonance sensors, Chem. Rev. 111 (2011) 3828-3857.
4. [4]
  [4] R. Jin, Y. Cao, C.A. Mirkin, et al., Photoinduced conversion of silver nanospheres to nanoprisms, Science 294 (2001) 1901-1903.
5. [5]
  [5] L.J. Sherry, R. Jin, C.A. Mirkin, G.C. Schatz, R.P. Van Duyne, Localized surface plasmon resonance spectroscopy of single silver triangular nanoprisms, Nano Lett. 6 (2006) 2060-2065.
6. [6]
  [6] M.G. Blaber, A.I. Henry, J.M. Bingham, G.C. Schatz, R.P. Van Duyne, LSPR imaging of silver triangular nanoprisms: correlating scattering with structure using electrodynamics for plasmon lifetime analysis, J. Phys. Chem. C 116 (2011) 393-403.
7. [7]
  [7] X.Y. Zhang, A. Hu, T. Zhang, et al., Self-assembly of large-scale and ultrathin silver nanoplate films with tunable plasmon resonance properties, ACS Nano 5 (2011) 9082-9092.
8. [8]
  [8] C.M. Tsai, M.S. Hsu, J.C. Chen, C.L. Huang, Mechanistic study of shape evolution of silver nanoprisms in the presence of KSCN, J. Phys. Chem. C 116 (2011) 461-467.
9. [9]
  [9] X.C. Jiang, Q.H. Zeng, A.B. Yu, Thiol-frozen shape evolution of triangular silver nanoplates, Langmuir 23 (2007) 2218-2223.
10. [10]
  [10] X.Q. Zou, S.J. Dong, Surface-enhanced Raman scattering studies on aggregated silver nanoplates in aqueous solution, J. Phys. Chem. B 110 (2006) 21545-21550.
11. [11]
  [11] S. Lin, M.M.K. Wong, P.K. Pat, et al., Cadmium sulfide silver nanoplate hybrid structure: synthesis and fluorescence enhancement, J. Phys. Chem. C 115 (2011) 21604-21609.
12. [12]
  [12] X. Le Guével, F.Y. Wang, O. Stranik, et al., Synthesis, stabilization, and functionalization of silver nanoplates for biosensor applications, J. Phys. Chem. C 113 (2009) 16380-16386.
13. [13]
  [13] K. Aslan, J.R. Lakowicz, C.D. Geddes, Rapid deposition of triangular silver nanoplates on planar surfaces: application to metal-enhanced fluorescence, J. Phys. Chem. B 109 (2005) 6247-6251.
14. [14]
  [14] L. Lu, A. Kobayashi, K. Tawa, Y. Ozaki, Silver nanoplates with special shapes: controlled synthesis and their surface plasmon resonance and surface-enhanced Raman scattering properties, Chem. Mater. 18 (2006) 4894-4901.
15. [15]
  [15] K.J. Barnham, A.I. Bush, Metals in Alzheimer’s and Parkinson’s diseases, Curr. Opin. Chem. Biol. 12 (2008) 222-228.
16. [16]
  [16] M. Kumar, N. Kumar, V. Bhalla, P.R. Sharma, T. Kaur, Highly selective fluorescence turn-on chemodosimeter based on rhodamine for nanomolar detection of copper ions, Org. Lett. 14 (2011) 406-409.
17. [17]
  [17] X. Zhang, X. Jing, T. Liu, et al., Dual-functional gadolinium-based copper(II) probe for selective magnetic resonance imaging and fluorescence sensing, Inorg. Chem. 51 (2012) 2325-2331.
18. [18]
  [18] E. Ballesteros, D. Moreno, T. Go´ mez, et al., A new selective chromogenic and turnon fluorogenic probe for copper(II) in water-acetonitrile 1:1 solution, Org. Lett. 11 (2009) 1269-1272.
19. [19]
  [19] B.C. Yin, B.C. Ye, W. Tan, H. Wang, C.C. Xie, An allosteric dual-DNAzyme unimolecular probe for colorimetric detection of copper(II), J. Am. Chem. Soc. 131 (2009) 14624-14625.
20. [20]
  [20] Y.T. Su, G.Y. Lan, W.Y. Chen, H.T. Chang, Detection of copper ions through recovery of the fluorescence of DNA-templated copper/silver nanoclusters in the presence of mercaptopropionic acid, Anal. Chem. 82 (2010) 8566-8572.
21. [21]
  [21] Y. Dong, R. Wang, G. Li, et al., Polyamine-functionalized carbon quantum dots as fluorescent probes for selective and sensitive detection of copper ions, Anal. Chem. 84 (2012) 6220-6224.
22. [22]
  [22] T. Lou, L. Chen, Z. Chen, et al., Colorimetric detection of trace copper ions based on catalytic leaching of silver-coated gold nanoparticles, ACS Appl. Mater. Inter. 3 (2011) 4215-4220.
23. [23]
  [23] J. Liu, Y. Lu, Colorimetric Cu²⁺ detection with a ligation DNAzyme and nanoparticles, Chem. Commun. (2007) 4872-4874.
24. [24]
  [24] X.Y. Xu, W.L. Daniel, W. Wei, C.A. Mirkin, Colorimetric Cu²⁺ detection using DNAmodified gold-nanoparticle aggregates as probes and click chemistry, Small 6 (2010) 623-626.
25. [25]
  [25] S.Q. Ye, X.H. Shi, W. Gu, Y.X. Zhang, Y.Z. Xian, A colorimetric sensor based on catechol-terminated mixed self-assembled monolayers modified gold nanoparticles for ultrasensitive detections of copper ions, Analyst 137 (2012) 3365-3371.
26. [26]
  [26] Y.M. Guo, Z. Wang, W. Qu, H.W. Shao, X.Y. Jiang, Colorimetric detection of mercury, lead and copper ions simultaneously using protein-functionalized gold nanoparticles, Biosens. Bioelectron. 26 (2011) 4064-4069.
27. [27]
  [27] Y.R. Ma, H.Y. Niu, X.L. Zhang, Y.Q. Cai, Colorimetric detection of copper ions in tap water during the synthesis of silver/dopamine nanoparticles, Chem. Commun. 47 (2011) 12643-12645.
28. [28]
  [28] W. Yang, J.J. Gooding, Z. He, Q. Li, G. Chen, Fast colorimetric detection of copper ions using L-cysteine functionalized gold nanoparticles, J. Nanosci. Nanotechnol. 7 (2007) 712-716.
29. [29]
  [29] Q. Zhang, N. Li, J. Goebl, Z. Lu, Y. Yin, A systematic study of the synthesis of silver nanoplates: is citrate a ‘‘magic’’ reagent? J. Am. Chem. Soc. 133 (2011) 18931-18939.
30. [30]
  [30] A. Rotaru, S. Dutta, E. Jentzsch, K. Gothelf, A. Mokhir, Selective dsDNA-templated formation of copper nanoparticles in solution, Angew. Chem. Int. Ed. 49 (2010) 5665-5667.
31. [31]
  [31] R. Jin, Y. Charles Cao, E. Hao, et al., Controlling anisotropic nanoparticle growth through plasmon excitation, Nature 425 (2003) 487-490.
32. [32]
  [32] S. Link, Z.L. Wang, M.A. El-Sayed, Alloy formation of gold-silver nanoparticles and the dependence of the plasmon absorption on their composition, J. Phys. Chem. B 103 (1999) 3529-3533.
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