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Citation: Li-Hui Kong, Da-Wei Fu, Qiong Ye, Heng-Yun Ye, Yi Zhang, Ren-Gen Xiong. Iso-structural phase transition in tetramethylammonium nickel(II) nitrite [(CH3)4N][Ni(NO2)3][J]. Chinese Chemical Letters, ;2014, 25(6): 844-848. doi: 10.1016/j.cclet.2014.05.028 shu

Iso-structural phase transition in tetramethylammonium nickel(II) nitrite [(CH3)4N][Ni(NO2)3]

  • 1.

    Ordered Matter Science Research Center, Southeast University, Nanjing 211189, China

  • Corresponding author: Qiong Ye,  Ren-Gen Xiong, 
  • Received Date: 8 April 2014
    Available Online: 14 May 2014

    Fund Project: This work was financially supported by the Project 973 (No. 2014CB848800) (No. 2014CB848800) Program for NCET and Ph.D. Programs Foundation of Ministry of Education of China (No. 20130092120013). (No. BK20130600)

  • The title compound, tetramethylammonium nickel nitrite [(CH3)4N][Ni(NO2)3], has a hexagonal perovskite-type structure with formula ABX3. It undergoes two reversible phase transitions occurring at about 409.1 and 428.4 K, associated with dielectric transitions. DSC measurement and dielectric measurement confirm the transition. The variable-temperature X-ray structural determinations and the powder X-ray diffraction (PXRD) experiments reveal that this compound has the same space group P3m1 (No. 164) at 293 K, 413 K and 438 K. The phase transitions are caused by the rotation of the [(CH3)4N]+ cation.
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