Citation: Rong-Mei Wen, Song-De Han, Hao Wang, Ying-Hui Zhang. Synthesis, structure and magnetic properties of manganese(II) coordination polymer with azido and zwitterionic dicarboxylate ligand[J]. Chinese Chemical Letters, ;2014, 25(6): 854-858. doi: 10.1016/j.cclet.2014.05.026 shu

Synthesis, structure and magnetic properties of manganese(II) coordination polymer with azido and zwitterionic dicarboxylate ligand

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Department of Chemistry, Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Nankai University, Tianjin 300071, China

Corresponding author: Ying-Hui Zhang,
Received Date: 15 April 2014
Available Online: 15 May 2014
Fund Project: This work was financially supported by MOE Innovation Team of China (No. IRT13022). (No. IRT13022)

A coordination polymer formulated as {[Mn₂L(N₃)₄]•2H₂O}_n(1) [L=1,4-bis(pyridinil-3-carboxylato)-l,4-dimethylbenzene] was synthesized and structurally and magnetically characterized. The uniform Mn(II) chains withmixed (μ-EO-N₃)₂(μ-COO) triple bridges (EO=end-on) are linked by L ligands to generate a 2-fold interpenetrating 3D framework. Meanwhile, magnetism analysis reveals antiferromagnetic coupling for 1.
- Manganese(II),
- Azido anion,
- Magnetism,
- 1,4-Bis(pyridinil-3-carboxylato)-l,4-,
- dimethylbenzene
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