Citation: Yin-Xia Sun, Wei-Yin Sun. Influence of temperature on metal-organic frameworks[J]. Chinese Chemical Letters, ;2014, 25(6): 823-828. doi: 10.1016/j.cclet.2014.04.032 shu

Influence of temperature on metal-organic frameworks

Yin-Xia Sun ^a,b ,
Wei-Yin Sun ^a,,

1.
a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China;
2.
b School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: Wei-Yin Sun,
Received Date: 18 March 2014
Available Online: 14 April 2014
Fund Project:

Reaction temperature is one of the key parameters in the synthesis ofmetal-organic frameworks (MOFs). Though there is no convergence with regard to the various experimental parameters, reaction temperature has been found to have remarkable influence on the formation and structure of MOFs, especially toward the control of topology and dimensionality of the MOF structures. Theoretically, the reaction temperature affects directly the reaction energy barrier in reaction thermodynamics and the reaction rate in the reaction kinetics. This review aims to show the influence of reaction temperature on crystal growth/assembly, structural modulation and transformation of MOFs, and to provide primary information and insights into the design and assembly of desired MOFs.
- Metal-organic frameworks (MOFs),
- Reaction temperature,
- Structural,
- transformation
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