Citation: Ying-Xia Wang, Tie-Hong Chen. A high dispersed Pt_0.35Pd_0.35Co_0.30/C as superior catalyst for methanol and formic acid electro-oxidation[J]. Chinese Chemical Letters, ;2014, 25(6): 907-911. doi: 10.1016/j.cclet.2014.04.031 shu

A high dispersed Pt_0.35Pd_0.35Co_0.30/C as superior catalyst for methanol and formic acid electro-oxidation

Ying-Xia Wang ,
Tie-Hong Chen ^,

1.
Institute of New Catalytic Materials Science, Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

Corresponding author: Tie-Hong Chen,
Received Date: 4 March 2014
Available Online: 8 April 2014
Fund Project: This work was supported by NSFC (No. 21373116) (No. 21373116) Tianjin Natural Science Research Fund (No. 13JCYBJC18300) (No. 13JCYBJC18300) RFDP (No. 20120031110005) (No. 20120031110005)MOE Innovation Team of China (No. IRT13022). (No. IRT13022)

Pt:Pd:Co ternary alloy nanoparticles were synthesized by sodium borohydride reduction under nitrogen, and were supported on carbon black as catalysts for methanol and formic acid electro-oxidation. Compared with Pt_0.65Co_0.30/C, Pt/C, Pd_0.65Co_0.30/C, and Pd/C catalyst, Pt_0.35Pd_0.35Co_0.30/C exhibited relatively high durability and strong poisoning resistance, and the Pt-mass activity was 3.6 times higher than that of Pt/C in methanol oxidation reaction. Meanwhile, the Pt_0.35Pd_0.35Co_0.30/C exhibited excellent activity with higher current density and higher CO tolerance than that of Pt_0.65Co_0.30/C, Pt/C, Pd_0.65Co_0.30/C, and Pd/C in formic acid electro-oxidation.
- Fuel cell,
- Ternary alloy,
- Formic acid oxidation,
- Methanol electro-oxidation
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沈阳化工大学材料科学与工程学院沈阳 110142

A high dispersed Pt0.35Pd0.35Co0.30/C as superior catalyst for methanol and formic acid electro-oxidation

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通讯作者: 陈斌, bchen63@163.com

A high dispersed Pt_0.35Pd_0.35Co_0.30/C as superior catalyst for methanol and formic acid electro-oxidation