Citation: Zhi-Jun Wei, Ye-Wei Xu, Lin Zhang, Mei-Ming Luo. Synthesis and thermal polymerization of perylene bisimide containing benzocyclobutene groups[J]. Chinese Chemical Letters, ;2014, 25(10): 1367-1370. doi: 10.1016/j.cclet.2014.04.022 shu

Synthesis and thermal polymerization of perylene bisimide containing benzocyclobutene groups

Zhi-Jun Wei ^a,c ,
Ye-Wei Xu ^b ,
Lin Zhang ^c,, ,
Mei-Ming Luo ^a,,

1.
a Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China;
2.
b Engineering Research Center of Biomass Materials, Ministry of Education, School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China;
3.
c Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900, China

Corresponding author: Lin Zhang, Mei-Ming Luo,
Received Date: 14 January 2014
Available Online: 10 April 2014
Fund Project:

Fourfold benzocyclobutene-functionalized perylene bisimide (PBI 4) has been synthesized and its structure was characterized by FTIR, MS and NMR. PBI 4 can react either with itself, or the appropriate dienophiles to form the corresponding products under appropriate temperature. The polymer film obtained from the reaction of PBI 4 with methyl vinyl silicone rubber possessed excellent film forming properties including flatness. The optical properties of PBI 4 and polymer film obtained from the reaction of PBI 4 and methyl vinyl silicone rubber have been determined by UV/vis and fluorescence spectroscopy.
- Perylene bisimide,
- Benzocyclobutene,
- Thermopolymerization,
- Optical properties
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