Citation: Tayyebeh Madrakian, Sara Heidari. Interaction of benzene-1,3-disulfonylamid-kriptofix[22] with iodine in chloroform and dichloromethane solutions[J]. Chinese Chemical Letters, ;2014, 25(10): 1375-1378. doi: 10.1016/j.cclet.2014.04.015 shu

Interaction of benzene-1,3-disulfonylamid-kriptofix[22] with iodine in chloroform and dichloromethane solutions

Tayyebeh Madrakian ^, ,
Sara Heidari

1.
Faculty of Chemistry, Bu-Ali Sina University, Hamedan 65174, Iran

Corresponding author: Tayyebeh Madrakian,
Received Date: 2 January 2014
Available Online: 8 April 2014

The interaction of iodine as an s-acceptor with a synthetic ligand, benzene-1,3-disulfonylamid-kriptofix [22] (BDSAK) as a p-donor has been investigated spectrophotometrically in chloroform (CHCl₃) and dichloromethane (DCM) solutions. The results of mole ratio plots and Job's method show the stoichiometry of complexation I₂/BDSAK is 1:1. Stability constants have been calculated in various temperatures and thermodynamic parameters have also been determined from the temperatures dependence of the stability constants by using van't Hoff equation. The results indicate the iodine complex with BDSAK is enthalpy stabilized but entropy destabilized.
- Charge transfer complex,
- Iodine,
- Spectrophotometry,
- Solvent effect
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