Citation:
Long-Wei Liang, Ke Du, Zhong-Dong Peng, Yan-Bing Cao, Guo-Rong Hu. Synthesis and electrochemical performance of LiNi0.6Co0.2Mn0.2O2 as a concentration-gradient cathode material for lithium batteries[J]. Chinese Chemical Letters,
;2014, 25(6): 883-886.
doi:
10.1016/j.cclet.2014.04.005
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Awell-ordered and spherical LiNi0.6Co0.2Mn0.2O2 cathode material was successfully synthesized from Ni and Mn concentration-gradient precursors via co-precipitation. The crystal structure, morphology and electrochemical properties of LiNi0.6Co0.2Mn0.2O2 were characterized by X-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy, and charge-discharge tests. The material delivered an initial discharge capacity of 174.3 mAh/g at 180 mA/g (1 C rate) between 2.8 and 4.3 V and more than 93.1% of that was retained after 100 cycles. In addition, it also exhibited excellent rate capability, high cut-off voltage and temperature performance.
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