Citation: Zhi-Hua Cui, Xiao-Hong Cheng, Xin Li, Hong-Hui Lu, Xi-Dong Wang, Wei-Guo Chen. Facile synthesis and properties of alkali-clearable azo disperse dye containing a carboxylic ester moiety[J]. Chinese Chemical Letters, ;2014, 25(8): 1121-1124. doi: 10.1016/j.cclet.2014.03.045 shu

Facile synthesis and properties of alkali-clearable azo disperse dye containing a carboxylic ester moiety

1.
a Engineering Research Center for Eco-Dyeing & Finishing of Textiles, Ministry of Education of China, Zhejiang Sci-Tech University, Hangzhou 310018, China;
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b Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education of China, Hangzhou 310018, China;
c Zhejiang Jihua Group Co.
c Zhejiang Jihua Group Co., Ltd., Hangzhou 311228, China

Corresponding author: Zhi-Hua Cui,
Received Date: 23 December 2013
Available Online: 19 March 2014
Fund Project: The work was supported by the National Natural Science Foundation of China (Nos. 51173168, 21106135) (Nos. 51173168, 21106135) Zhejiang Provincial Key Innovation Team (No. 2010R50038) (No. 2010R50038)

A yellow, alkali-clearable azo disperse dye containing a carboxylic ester moiety was readily synthesized from the reactant p-aminobenzoic acid by successive diazotization, coupling reaction, chlorination and esterification with ethanol. Then its molecular structure was characterized by FTIR, ¹H NMR, ¹³C NMR, mass spectrometry and elemental analysis. The synthesized dye and a similar control dye containing the acylamide moiety (Ⅰ) were applied to dyeing poly(ethylene terephthalate) fabric and their washing and rubbing fastness properties with different post-treatment methods (reduction clearing and alkali clearing) were examined and compared. It is found that the ester-containing disperse dye shows good alkali-clear ability on poly(ethylene terephthalate) fabric and contaminates little to environment due to the absence of reductants, as well as low toxicity and easy recycling of the hydrolysates.
- Alkali-clearable,
- Synthesis,
- Carboxylic ester,
- Disperse dye,
- PET
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