Citation: Chun-Lei Yang, Xu-Hai Zhang, Guo Lan, Lu-Yang Chen, Ming-Wei Chen, Yu-Qiao Zeng, Jian-Qing Jiang. Pd-based nanoporous metals for enzyme-free electrochemical glucose sensors[J]. Chinese Chemical Letters, ;2014, 25(4): 496-500. doi: 10.1016/j.cclet.2014.02.001 shu

Pd-based nanoporous metals for enzyme-free electrochemical glucose sensors

1.
a Jiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China;
2.
b Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan

Corresponding author: Yu-Qiao Zeng,
Received Date: 24 October 2013
Available Online: 8 January 2014
Fund Project: This work is supported by the National Science Foundation of China (Nos. 51001026, 21173041) (Nos. 51001026, 21173041) the Project-sponsored by SRF for ROCS, SEM (No. 6812000013) (No. 6812000013) the Project-sponsored by Nanjing for ROCS (No. 7912000011) (No. 7912000011) Opening Project of Jiangsu Key Laboratory of Advanced Metallic Materials (No. AMM201101) (No. AMM201101)

Nanoporous metals (NPMs) show potential applications as enzyme-free glucose sensors. There are few reports on nanoporous Pd in this area even though their cost is much lower than other NPMs. In this work, we report the formation of Pd-based NPM with improved catalytic activity towards the oxidation of glucose. By dealloying metallic glasses, Pd-based NPMs with bi-continuous networks were obtained. All the Pd-based NPMs show high electrochemical catalytic activity towards glucose oxidation. In this study, NPM with an open, three-dimensional, ligament-channel nanoporous structure resulted by dealloying metallic Pd₃₀Cu₄₀Ni₁₀P₂₀, producing a pore size of 11 nm and a ligament size of 7 nm as the best configuration towards the direct oxidation reaction of glucose.
- Glucose sensors,
- Pd-based NPM,
- Dealloying,
- Electrochemical
1. [1]
  [1] A. Heller, B. Feldman, Electrochemical glucose sensors and their applications in diabetes management, Chem. Rev. 108 (2008) 2482-2505.
2. [2]
  [2] J. Wang, Electrochemical glucose biosensors, Chem. Rev. 108 (2008) 814-825.
3. [3]
  [3] X.Y. Wang, S.Q. Liu, K.L. Huang, et al., Fixation of CO2 by electrocatalytic reduction to synthesis of dimethyl carbonate in ionic liquid using effective silver-coated nanoporous copper composites, Chin. Chem. Lett. 21 (2010) 987-990.
4. [4]
  [4] S. Park, T.D. Chung, H.C. Kim, Nonenzymatic glucose detection using mesoporous platinum, Anal. Chem. 75 (2003) 3046-3049.
5. [5]
  [5] J. Wang, D.F. Thomas, A. Chen, Nonenzymatic electrochemical glucose sensor based on nanoporous PtPb network, Anal. Chem. 80 (2003) 997-1004.
6. [6]
  [6] S. Park, H. Boo, T.D. Chung, Electrochemical non-enzymatic glucose sensors, Anal. Chim. Acta 556 (2006) 46-57.
7. [7]
  [7] C.X. Xu, Y.Q. Liu, F. Su, et al., Nanoporous PtAg and PtCu alloys with hollow ligament for enhanced electrocatalysis and glucose biosensing, Biosens. Bioelectron. 27 (2011) 160-166.
8. [8]
  [8] D. van Noort, C.F. Mandenius, Porous gold surface for biosensor applications, Biosens Bioelectron. 15 (2000) 203-209.
9. [9]
  [9] Z. Liu, L. Huang, L. Zhang, et al., Electrocatalytic oxidation of D-glucose at nanoporous Au and Au-Ag alloy electrodes in alkaline aqueous solutions, Electrochim. Acta 54 (2009) 7286-7293.
10. [10]
  [10] Y. Ding, Y.J. Kim, J. Erlebacher, Nanoporous gold leaf: "Ancient technology"/advanced material, J. Adv. Mater. 16 (2004) 1897-1900.
11. [11]
  [11] H.M. Yin, C.Q. Zhou, C. Xu, et al., Aerobic oxidation of D-glucose on support-free nanoporous gold, J. Phys. Chem. C 112 (2008) 9673-9678.
12. [12]
  [12] N. Tavakkoli, S. Nasrollahi, Non-enzymatic glucose sensor based on palladium coated nanoporous gold film electrode, Aust. J. Chem. 66 (2013) 1097-1104.
13. [13]
  [13] H.Y. Bai, M. Han, Y.Z. Du, et al., Facile synthesis of porous tubular palladium nanostructures and their application in a nonenzymatic glucose sensor, Chem. Commun. 46 (2010) 1739-1741.
14. [14]
  [14] X. Chen, Z. Cai, Z. Lin, et al., A novel non-enzymatic ECL sensor for glucose using palladium nanoparticles supported on functional carbon nanotubes, Biosens Bioelectron. 24 (2009) 3475-3480.
15. [15]
  [15] J. Erlebacher, An atomistic description of dealloying porosity evolution, the critical potential, and rate-limiting behavior, J. Electrochem. Soc. 151 (2004) C614-C626.
16. [16]
  [16] J.L. Xu, Y. Wang, Z.H. Zhang, Potential and concentration dependent electrochemical dealloying of Al2Au in sodium chloride solutions, J. Phys. Chem. C 116 (2012) 5689-5699.
17. [17]
  [17] J. Erlebacher, M.J. Aziz, A. Karma, et al., Evolution of nanoporosity in dealloying, Nature 410 (2001) 450-453.
18. [18]
  [18] L.H. Qian, M.W. Chen, Ultrafine nanoporous gold by low temperature dealloying and kinetics of nanopore formation, Appl. Phys. Lett. 91 (2007) 083105-183105.
19. [19]
  [19] Y. Kuang, B. Wu, D. Hu, et al., One-pot synthesis of highly dispersed palladium nanoparticles on acetylenic ionic liquid polymer functionalized carbon nanotubes for electrocatalytic oxidation of glucose, J. Solid State Electrochem. 16 (2012) 759-766.
20. [20]
  [20] L.Y. Chen, X.Y. Lang, T. Fujita, et al., Nanoporous gold for enzyme-free electrochemical glucose sensors, Scr. Mater. 65 (2011) 17-20.
1. [1]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
2. [2]
  Chunxiu Yu , Zelin Wu , Hongle Shi , Lingyun Gu , Kexin Chen , Chuan-Shu He , Yang Liu , Heng Zhang , Peng Zhou , Zhaokun Xiong , Bo Lai . Insights into the electron transfer mechanisms of peroxydisulfate activation by modified metal-free acetylene black for degradation of sulfisoxazole. Chinese Chemical Letters, 2024, 35(8): 109334-. doi: 10.1016/j.cclet.2023.109334
3. [3]
  Guan-Nan Xing , Di-Ye Wei , Hua Zhang , Zhong-Qun Tian , Jian-Feng Li . Pd-based nanocatalysts for oxygen reduction reaction: Preparation, performance, and in-situ characterization. Chinese Journal of Structural Chemistry, 2023, 42(11): 100021-100021. doi: 10.1016/j.cjsc.2023.100021
4. [4]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
5. [5]
  Chenghao Liu , Xiaofeng Lin , Jing Liao , Min Yang , Min Jiang , Yue Huang , Zhizhi Du , Lina Chen , Sanjun Fan , Qitong Huang . Carbon dots-based dopamine sensors: Recent advances and challenges. Chinese Chemical Letters, 2024, 35(12): 109598-. doi: 10.1016/j.cclet.2024.109598
6. [6]
  Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
7. [7]
  Jingxuan Liu , Shiqi Zhao , Xiang Wu . Flexible electrochemical capacitor based NiMoSSe electrode material with superior cycling and structural stability. Chinese Chemical Letters, 2024, 35(7): 109059-. doi: 10.1016/j.cclet.2023.109059
8. [8]
  Jie Zhou , Chuanxiang Zhang , Changchun Hu , Shuo Li , Yuan Liu , Zhu Chen , Song Li , Hui Chen , Rokayya Sami , Yan Deng . Electrochemical aptasensor based on black phosphorus-porous graphene nanocomposites for high-performance detection of Hg²⁺. Chinese Chemical Letters, 2024, 35(11): 109561-. doi: 10.1016/j.cclet.2024.109561
9. [9]
  Kezuo Di , Jie Wei , Lijun Ding , Zhiying Shao , Junling Sha , Xilong Zhou , Huadong Heng , Xujing Feng , Kun Wang . A wearable sensor device based on screen-printed chip with biofuel cell-driven electrochromic display for noninvasive monitoring of glucose concentration. Chinese Chemical Letters, 2025, 36(2): 109911-. doi: 10.1016/j.cclet.2024.109911
10. [10]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
11. [11]
  Jiqing Liu , Qi Dang , Liting Wang , Dejin Wang , Liang Tang . Applications of flexible electrochemical electrodes in wastewater treatment: A review. Chinese Chemical Letters, 2024, 35(8): 109277-. doi: 10.1016/j.cclet.2023.109277
12. [12]
  Xueling Yu , Lixing Fu , Tong Wang , Zhixin Liu , Na Niu , Ligang Chen . Multivariate chemical analysis: From sensors to sensor arrays. Chinese Chemical Letters, 2024, 35(7): 109167-. doi: 10.1016/j.cclet.2023.109167
13. [13]
  Yang Yang , Jing-Li Luo , Xian-Zhu Fu . Water-oxidation intermediates enabling electrochemical propylene epoxidation. Chinese Journal of Structural Chemistry, 2024, 43(5): 100269-100269. doi: 10.1016/j.cjsc.2024.100269
14. [14]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
15. [15]
  Chuang LIU , Lichao SUN , Qingfeng ZHANG . Chiral inorganic nanocatalysts for electrochemical and enzyme-mimicked biosensing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 59-78. doi: 10.11862/CJIC.20240406
16. [16]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
17. [17]
  Tianli Hui , Tao Zheng , Xiaoluo Cheng , Tonghui Li , Rui Zhang , Xianghai Meng , Haiyan Liu , Zhichang Liu , Chunming Xu . A review of plasma treatment on nano-microstructure of electrochemical water splitting catalysts. Chinese Journal of Structural Chemistry, 2025, 44(3): 100520-100520. doi: 10.1016/j.cjsc.2025.100520
18. [18]
  Erzhuo Cheng , Yunyi Li , Wei Yuan , Wei Gong , Yanjun Cai , Yuan Gu , Yong Jiang , Yu Chen , Jingxi Zhang , Guangquan Mo , Bin Yang . Galvanostatic method assembled ZIFs nanostructure as novel nanozyme for the glucose oxidation and biosensing. Chinese Chemical Letters, 2024, 35(9): 109386-. doi: 10.1016/j.cclet.2023.109386
19. [19]
  Lin Guo , Rui Xu , Denys Makarov . Printable magnetoresistive sensors: A crucial step toward unconventional magnetoelectronics. Chinese Journal of Structural Chemistry, 2025, 44(2): 100428-100428. doi: 10.1016/j.cjsc.2024.100428
20. [20]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(618)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142