Citation: Dan Liu, Yong-Min Guo, Yi Li, Bao-Zong Li. Characterization of single-handed, coiled, carbonaceous, tubular nanoribbons[J]. Chinese Chemical Letters, ;2014, 25(6): 879-882. doi: 10.1016/j.cclet.2014.01.039 shu

Characterization of single-handed, coiled, carbonaceous, tubular nanoribbons

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Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Corresponding author: Bao-Zong Li,
Received Date: 2 December 2013
Available Online: 16 January 2014
Fund Project: This work was supported by Natural Science Foundation of Jiangsu Province (No. BK2011354) (No. BK2011354) the Priority Academic Program Development of Jiangsu High Education Institutions (PAPD) (PAPD)

Left-handed, coiled, 4,4'-biphenylene bridged polybissilsesquioxane, tubular nanoribbons were prepared according to the published literature. After carbonization and removal of silica using HF aqueous solution, left-handed, coiled, carbonaceous, tubular nanoribbons were obtained. The lefthanded, coiled, carbonaceous, tubular nanoribbons were characterized using field-emission scanning electron microscopy, transmission electron microscopy, powder X-ray diffraction, Raman spectrophotometer, diffuse reflectance circular dichroism (DRCD), and N₂ adsorptions. Micropores were formed due to the removal of silica. The nitrogen BET surface area is 1727 m²/g. A broad, positive DRCD signal, identified at 40'-800 nm, indicates the carbonaceous, tubular nanoribbons exhibit optical activity. The helical pitch is proposed to play an important role in the position of the DRCD signal.
- Nanoparticles,
- Carbon/silica,
- Sol-gel preparation,
- Structural
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