Citation: Nga-Chun Ng, Mian HR Mahmood, Hai-Yang Liu, Fei Yam, Lam-Lung Yeung, Chi-K. Chang. Appended corrole manganese complexes：Catalysis and axial-ligand effect[J]. Chinese Chemical Letters, ;2014, 25(4): 571-574. doi: 10.1016/j.cclet.2014.01.027 shu

Appended corrole manganese complexes：Catalysis and axial-ligand effect

1.
a Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, Hong Kong University of Science and Technology, Hong Kong, China;
2.
b Department of Chemistry, South China University of Technology, Guangzhou 510641, China;
c Department of Chemistry, Michigan State University, E.
c Department of Chemistry, Michigan State University, E. Lansing, MI 48824, USA

Corresponding author: Hai-Yang Liu, Chi-K. Chang,
Received Date: 10 October 2013
Available Online: 30 December 2013
Fund Project: This work was supported by National Natural Science Foundation of China (Nos. 21171057, 21371059). Research Grant Council of Hong Kong under project HKUST6182/99p and Area of Excellence Scheme (No. AoE/P-10/01). (Nos. 21171057, 21371059)

A series of N-base appended corroles and their manganese complexes were synthesized and their binding constants with three different nitrogenous ligands, triethylamine, N-methylimidazole and pyridine, were evaluated by spectroscopy. Kinetic studies indicated that the presence of appended Ndonor ligands may cause a significant enhancement of the rate of oxygen atom transfers (OAT) from (oxo)manganese(Ⅴ) corrole to alkene, and the stronger axial ligand binding has impact on the rate of the oxidation reaction. Turnover frequency (TOF) for the catalytic oxidation of alkenes by appended manganese corroles varies with the following ligand order: acetamido < pyridyl < imidazolyl. The influence of the external axial ligands on the catalytic epoxidation was investigated by using appended acetamido manganese corrole as catalyst, with the results revealing that N-methylimidazole gave the best enhancement on the yields of total oxidation products among the investigated nitrogenous ligands.
- Manganese,
- Corrole,
- Catalysis,
- Axial-ligand,
- Oxygen atom transfer
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