Citation: Jia Zhao, Lei Ma, Xiao-Liang Xu, Feng Feng, Xiao-Nian Li. Synthesis of carbon-supported Pd/SnO₂ catalyst for highly selective hydrogenation of 2,4-difluoronitrobenzene[J]. Chinese Chemical Letters, ;2014, 25(8): 1137-1140. doi: 10.1016/j.cclet.2014.01.024 shu

Synthesis of carbon-supported Pd/SnO₂ catalyst for highly selective hydrogenation of 2,4-difluoronitrobenzene

1.
Industrial Catalysis Institute of Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: Xiao-Nian Li,
Received Date: 22 October 2013
Available Online: 31 December 2013
Fund Project:

Halogenated anilines have a wide range of applications in the production of pharmaceuticals and agrochemical substances, and thus it is of great importance to develop highly active and selective catalysts for the hydrogenation of halogenated nitrobenzenes. We approach this challenge by probing noble metal/non-noble metal oxide nanoparticles (NPs) catalysts. Carbon-supported Pd/SnO₂ catalysts were synthesized by the chemical reduction method, and their catalytic activity was evaluated by the hydrogenation reaction of 2,4-difluoronitrobenzene (DFNB) to the corresponding 2,4-difluoroaniline (DFAN), showing a remarkable synergistic effect of the Pd and SnO₂ NPs. The as-prepared Pd/SnO₂/C catalysts were characterized using TEM, XRD, H₂ TPD and XPS techniques. Modifications to the electronic structure of the Pd atoms through the use of SnO₂ led to the suppression of the hydrogenolysis of the C-F bond and the acceleration of nitrosobenzene (DFNSB) conversion and consequently, resulted in the inhibition of the formation of reactive by-products and may be responsible for the enhancements observed in selectivity.
- Tin dioxide,
- Palladium,
- Selective hydrogenation,
- 2,4-Difluoronitrobenzene
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of carbon-supported Pd/SnO2 catalyst for highly selective hydrogenation of 2,4-difluoronitrobenzene

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通讯作者: 陈斌, bchen63@163.com

Synthesis of carbon-supported Pd/SnO₂ catalyst for highly selective hydrogenation of 2,4-difluoronitrobenzene