Citation: Yuan Zhang, Chen-Yan Wei, Tian-Fu Liu. Structure and magnetic property of bimetallic hexanuclear cluster based on 5-chlorosalicylaldehyde oxime[J]. Chinese Chemical Letters, ;2014, 25(6): 937-940. doi: 10.1016/j.cclet.2014.01.009 shu

Structure and magnetic property of bimetallic hexanuclear cluster based on 5-chlorosalicylaldehyde oxime

1.
School of Chemistry, Beijing Institute of Technology, Beijing 100081, China

Corresponding author: Tian-Fu Liu,
Received Date: 24 September 2013
Available Online: 18 December 2013
Fund Project: We are grateful for financial support from the Natural Science Foundation of China (NSFC) (No. 21171021) (NSFC) Beijing National Laboratory for Molecular Sciences (BNLMS) (BNLMS)

The bimetallic hexanuclear cluster [Mn₄Ni₂O₂(Cl-Sao)₆•(CH₃OH)₈]•10CH₃OH (1) was synthesized. Single-crystal X-ray analysis reveals that 1 consists of two [Mn₂Ni(μ₃-O)(Cl-Sao)₃] subunits linked together via two pairs of long Ni-O bonds involving two oximate oxygen atoms and two phenolate oxygen atoms. Each Mn and Ni center achieves six-coordination with axialmethanol molecules. The spin centers of the Mn^III and Ni^II ions exchange magnetic coupling through O^2-, O_phenolate^- and -N-O-bridges. The magnetic properties of the cluster have been investigated.
- Cluster,
- Crystal structure,
- Magnetic property,
- Manganese complex,
- Nickel complex
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沈阳化工大学材料科学与工程学院沈阳 110142