Citation: Zi-Lan Feng, Yuan-Yuan Yao, Jing-Kun Xu, Long Zhang, Zi-Fei Wang, Yang-Ping Wen. One-step co-electrodeposition of graphene oxide doped poly(hydroxymethylated-3,4-ethylenedioxythiophene) film and its electrochemical studies of indole-3-acetic acid[J]. Chinese Chemical Letters, ;2014, 25(4): 511-516. doi: 10.1016/j.cclet.2014.01.004 shu

One-step co-electrodeposition of graphene oxide doped poly(hydroxymethylated-3,4-ethylenedioxythiophene) film and its electrochemical studies of indole-3-acetic acid

Zi-Lan Feng ^a,b ,
Yuan-Yuan Yao ^a ,
Jing-Kun Xu ^a,, ,
Long Zhang ^a ,
Zi-Fei Wang ^a,b ,
Yang-Ping Wen ^b,,

1.
a Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China;
2.
b College of Science, Jiangxi Agricultural University, Nanchang 330045, China

Corresponding author: Jing-Kun Xu, Yang-Ping Wen,
Received Date: 24 October 2013
Available Online: 17 December 2013
Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 51263010, 51272096) (Nos. 51263010, 51272096) Jiangxi Provincial Department of Education (No. GJJ11590) (No. GJJ11590)

A novel graphene oxide (GO) doped poly(hydroxymethylated-3,4-ethylenedioxythiophene) (PEDOTM) film has been achieved via one-step co-electrodeposition and utilized for electrochemical studies of indole-3-acetic acid (IAA). The incorporation of GO into PEDOTM film facilitated the electrocatalytic activity and exhibited a favorable interaction between the PEDOTM/GO film and the phytohormone during the oxidation of IAA. Under optimized conditions, differential pulse voltammetry and square wave voltammetry were used for the quantitative analysis of IAA, respectively, each exhibiting a wide linearity range from 0.6 μmol L^-1 to 10 μmol L^-1 and 0.05 μmol L^-1 to 40 μmol L^-1, good sensitivity with a low detection limit of 0.087 μmol L^-1 and 0.033 μmol L^-1, respectively, as well as good stability. With the notable advantages of a green, sensitive method, expeditious response and facile operation, the as-prepared PEDOTM/GO organic-inorganic composite film provides a promising platform for electrochemical studies of IAA.
- Co-electrodeposition,
- EDOT derivatives,
- Graphene oxide,
- Indole-3-acetic acid
1. [1]
  [1] L.B. Groenendaal, G. Zotti, P.H. Aubert, et al., Electrochemistry of poly(3,4-alkylenedioxythiophene) derivatives, Adv. Mater. 15 (2003) 855-879.
2. [2]
  [2] S. Kirchmeyer, A. Elschner, K. Reuter, et al., PEDOT as a Conductive Polymer: Principles and Applications, CRC Press, New York, 2010.
3. [3]
  [3] Y.P. Wen, L.M. Lu, D. Li, et al., Ascorbate oxidase electrochemical biosensor based on the biocompatible poly(3,4-ethylenedioxythiophene) matrices for agricultural application in crops, Chin. Chem. Lett. 23 (2012) 221-224.
4. [4]
  [4] Y.P. Wen, D. Li, Y. Lu, et al., Poly(3,4-ethylenedioxythiophene methanol)/ascorbate oxidase/nafion-single-walled carbon nanotubes biosensor for voltammetric detection of vitamin C, Chin. J. Polym. Sci. 30 (2012) 460-469.
5. [5]
  [5] Y. Lu, Y.P. Wen, B.Y. Lu, et al., Electrosynthesis and characterization of poly(hydroxymethylated- 3,4-ethylenedioxythiophene) film in aqueous micellar solution and its biosensing application, Chin. J. Polym. Sci. 30 (2012) 824-836.
6. [6]
  [6] L.P. Wu, L.M. Lu, L. Zhang, et al., Electrochemical determination of the anticancer herbal drug shikonin at a nanostructured poly(hydroxymethylated-3,4-ethylenedioxythiophene) modified electrode, Electroanalysis 25 (2013) 1-7.
7. [7]
  [7] L.J. Cote, R. Cruz-Silva, J. Huang, Flash reduction and patterning of graphite oxide and its polymer composite, J. Am. Chem. Soc. 131 (2009) 11027-11032.
8. [8]
  [8] Y.Q. He, N.N. Zhang, Y. Liu, et al., Facile synthesis and excellent catalytic activity of gold nanoparticles on graphene oxide, Chin. Chem. Lett. 23 (2012) 41-44.
9. [9]
  [9] Y.Q. He, N.N. Zhang, X.D. Wang, Adsorption of graphene oxide/chitosan porous materials for metal ions, Chin. Chem. Lett. 22 (2011) 859-862.
10. [10]
  [10] Y.S. Feng, J.J. Ma, X.Y. Lin, et al., Covalent functionalization of graphene oxide by 9- (4-aminophenyl)acridine and its derivatives, Chin. Chem. Lett. 23 (2012) 1411- 1414.
11. [11]
  [11] D. Li, M.B. Müller, S. Glije, et al., Processable aqueous dispersions of graphene nanosheets, Nat. Nanotechol. 3 (2008) 101-105.
12. [12]
  [12] A. Österholma, T. Lindfors, J. Kauppila, et al., Electrochemical incorporation of graphene oxide into conducting polymer films, Electrochim. Acta 83 (2012) 463- 470.
13. [13]
  [13] W.M. Si, W. Lei, Q.L. Hao, et al., Electrodeposition of graphene oxide doped poly(3, 4-ethylenedioxythiophene) film and its electrochemical sensing of catechol and hydroquinone, Electrochim. Acta 85 (2012) 295-301.
14. [14]
  [14] C.Z. Zhu, J.F. Zhai, S.J. Dong, et al., Graphene oxide/polypyrrole nanocomposites: one-step electrochemical doping, coating and synergistic effect for energy storage, J. Mater. Chem. 22 (2012) 6300-6306.
15. [15]
  [15] C. Uggla, E.J. Mellerowicz, B. Sundberg, Indole-3-acetic acid controls cambial growth in scots pine by positional signaling, Plant Physiol. 117 (1998) 113-121.
16. [16]
  [16] Y.L. Zhou, Z.N. Xu, M. Wang, et al., Electrochemical immunoassay platform for high sensitivity detection of indole-3-acetic acid, Electrochim. Acta 96 (2013) 66-73.
17. [17]
  [17] H.S. Yin, Z.N. Xu, Y.L. Zhou, et al., An ultrasensitive electrochemical immunosensor platform with double signal amplification for indole-3-acetic acid determinations in plant seeds, Analyst 138 (2013) 1851-1857.
18. [18]
  [18] S.J. Hou, J. Zhu, M.Y. Ding, et al., Simultaneous determination of gibberellic acid, indole-3-acetic acid and abscisic acid in wheat extracts by solid-phase extraction and liquid chromatography-electrospray tandem mass spectrometry, Talanta 76 (2008) 798-802.
19. [19]
  [19] Y.L. Wu, B. Hu, Simultaneous determination of several phytohormones in natural coconut juice by hollow fiber-based liquid-liquid-liquid microextraction-high performance liquid chromatography, J. Chromatogr. A 1216 (2009) 7657-7663.
20. [20]
  [20] T. Gan, C.G. Hu, Z.L. Chen, et al., A disposable electrochemical sensor for the determination of indole-3-acetic acid based on poly(safranine T)-reduced graphene oxide nanocomposite, Talanta 85 (2011) 310-316.
21. [21]
  [21] B. Sun, L.J. Chen, Y. Xu, et al., Ultrasensitive photoelectrochemical immunoassay of indole-3-acetic acid based on the MPA modified CdS/RGO nanocomposites decorated ITO electrode, Biosens. Bioelectron. 51 (2014) 164-169.
22. [22]
  [22] I. Gualandi, E. Scavetta, S. Zappoli, et al., Electrocatalytic oxidation of salicylic acid by a cobalt hydrotalcite-like compound modified Pt electrode, Biosens. Bioelectron. 26 (2011) 3200-3206.
23. [23]
  [23] F. Sundfors, J. Bobacka, A. Ivaska, et al., Kinetics of electron transfer between Fe(CN)₆^3-/^4- and poly(3,4-ethylenedioxythiophene) studied by electrochemical impedance spectroscopy, Electrochim. Acta 47 (2002) 2245-2251.
24. [24]
  [24] F.X. Jiang, Z.Q. Yao, R.R. Yue, et al., Electrochemical fabrication of long-term stable Pt-loaded PEDOT/graphene composites for ethanol electrooxidation, Int. J. Hydrogen Energy 37 (2012) 14085-14093.
25. [25]
  [25] Z. Mousavi, J. Bobacka, A. Ivaska, et al., Poly(3,4-ethylenedioxythiophene) (PEDOT) doped with carbon nanotubes as ion-to-electron transducer in polymer membrane-based potassium ion-selective electrodes, J. Electroanal. Chem. 633 (2009) 246-252.
26. [26]
  [26] R.S. Nicholson, Theory and application of cyclic voltammetry for measurement of electrode reaction kinetics, Anal. Chem. 37 (1965) 1351-1355.
27. [27]
  [27] R.A. de Toledo, C.M.P. Vaz, Use of a graphite-polyurethane composite electrode for electroanalytical determination of indole-3-acetic acid in soil samples, Microchem. J. 86 (2007) 161-165.
28. [28]
  [28] L. Henández, P. Henández, F. Patón, Adsorptive stripping determination of indole- 3-acetic acid at a carbon fiber ultramicroelectrode, Anal. Chim. Acta 327 (1996) 117-123.
29. [29]
  [29] R.Z.Wang, L.T. Xiao, et al.,Amperometricdeterminationof indoc-3-acetic acidbased on platinum nanowires and nanotubes, Chin. Chem. Lett. 17 (2006) 1585-1588.
30. [30]
  [30] L.N. Huang, Study on Electrochemical Biosensor for the Detection of Phytohormone IAA, Hunan Agricultural University, Changsha, Hunan, China, 2011.
31. [31]
  [31] J. Bulíčková, R. Sokolová, S. Giannarelli, et al., Determination of plant hormone indole-3-acetic acid in aqueous solution, Electroanalysis 25 (2013) 303-307.
32. [32]
  [32] K.B. Wu, Y.L. Sun, S.S. Hu, Development of an amperometric indole-3-acetic acid sensor based on carbon nanotubes film coated glassy carbon electrode, Sens. Actuators B: Chem. 96 (2003) 658-662.
33. [33]
  [33] G.N. Chen, Z.F. Zhao, X.L. Wang, et al., Electrochemical behavior of tryptophan and its derivatives at a glassy carbon electrode modified with hemin, Anal. Chim. Acta 452 (2002) 245-254.
34. [34]
  [34] S. Mancuso, A.M. Marras, V. Magnus, et al., Noninvasive and continuous recordings of auxin fluxes in intact root apex with a carbon nanotube-modified and selfreferencing microelectrode, Anal. Biochem. 341 (2005) 344-351.
35. [35]
  [35] Y.J. Yang, X.W. Xiong, K.K. Hou, et al., The amperometric determination of indole- 3-acetic acid based on CeCl3-DHP film modified gold electrode, Russ. J. Electrochem. 47 (2011) 47-52.
36. [36]
  [36] Y. Yardim, M.E. Erez, Electrochemical behavior and electroanalytical determination of indole-3-acetic acid phytohormone on a boron-doped diamond electrode, Electroanalysis 23 (2011) 667-673.
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