Citation: Ali Reza Pourali, Mehrosadat Tabaean, S. Mohamad Reza Nazifi. A novel and selective oxidation of benzylic alcohols with polymer-supported periodic acid under mild aprotic conditions[J]. Chinese Chemical Letters, ;2012, 23(1): 21-24. doi: 10.1016/j.cclet.2011.07.022 shu

A novel and selective oxidation of benzylic alcohols with polymer-supported periodic acid under mild aprotic conditions

School of Chemistry, Damghan University, Damghan 36715/364, Iran

Received Date: 26 May 2011

Fund Project: We are grateful to The Damghan University Research Council for the partial support of this work.

A new polymeric oxidizing reagent was prepared by supporting periodic acid on poly(1,4-phenylene-2,5-pyridine dicarboxyamide). This polymeric reagent was used for the selective oxidation of primary benzylic alcohols to the corresponding benzaldehydes in CH₃CN at reflux conditions. Excellent selectivity was observed between primary benzyl alcohols and secondary ones as well as non-benzylic alcohols in the oxidation reactions. Allylic alcohols were also converted to the corresponding aldehydes with good yields.
- Oxidation,
- Benzylic alcohol,
- Polymer-supported reagent,
- Periodate
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