Citation: Jie Ping Shi, Hui Yang, Li Wei, Hong Wen Hu, Guo Yuan Lu. Synthesis and nonlinear optical properties of copolymers of fluoro-containing bisphenol A and chromophores[J]. Chinese Chemical Letters, ;2011, 22(11): 1367-1370. doi: 10.1016/j.cclet.2011.05.006 shu

Synthesis and nonlinear optical properties of copolymers of fluoro-containing bisphenol A and chromophores

Department of Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Received Date: 21 February 2011

Fund Project: This work was supported by the National Natural Science Foundation (No.20774039) and the National Basic Research Program of China (No.2007CB925103).We acknowledge gratefully Prof.Wang Chang-Shun and Dr.He Ting-Chao in Shanghai Jiao Tong University for the measurements of macroscopic nonlinear optical coefficient.

A series of new fluoro-containing copolymers have been synthesized by a Mitsunobu reaction with 4, 4'-(hexafluoro-isopropylidene)bisphenol A (6FBPA) and the corresponding N, N-dihydroxyethylaminoaryl azo or ring-locked triene compounds, which have high thermal stability and good solubility in organic solvents. The nonlinear optical (NLO) measurements made by Marker fringe method at 1064 nm indicate that the copolymers embedded with the ring-locked triene and azo chromophores exhibit higher macroscopic nonlinear optical coefficient (70.2 pm/V and 26.5-34.6 pm/V, respectively). Thermal analysis and UV-visible absorption spectra show that the copolymers have good thermal stability (T_d=264-319℃) and optical transparency (λ_max<500nm).
- NLO materials,
- NLO chromophores,
- Ring-locked triene,
- Mitsunobu reaction
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