Citation: Sun Lin Feng, Chuan Zhi Liu, Qiang Li, Xiao Chun Yu, Qing Xu. Rhodium-catalyzed aerobic N-alkylation of sulfonamides with alcohols[J]. Chinese Chemical Letters, ;2011, 22(9): 1021-1024. doi: 10.1016/j.cclet.2011.03.014 shu

Rhodium-catalyzed aerobic N-alkylation of sulfonamides with alcohols

College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China

Received Date: 23 November 2010

Fund Project: We are grateful to the National Natural Science Foundation of China (No. 20902070), Natural Science Foundation of Zhejiang Province (No. Y4100579) and Qianjiang Talents Program (No. QJD0902004) of Zhejiang Province for financial supports.

By using the famous Wilkinson's catalyst, N-alkylation of sulfonamides can be easily realized under mild aerobic conditions by using alcohols as the alkylating reagent, giving monoalkylated sulfonamides in high yields and selectivities with water produced as the only byproduct. This advantageous aerobic method is potentially general in substrate scope that it can also be applied to other amides, amines and alcohols.
- Alcohols,
- Sulfonamides,
- Rhodium catalyst,
- N-Alkylation reaction,
- Aerobic reaction
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