Citation: U. M. Rao Kunda, V. N. Reddy Mudumala, C. S. Reddy Gangireddy, B. R. Nemallapudi, K. N. Sandip, S. R. Cirandur. Amberlyst-15 catalyzed synthesis of alkyl/aryl/heterocyclic phosphonates[J]. Chinese Chemical Letters, ;2011, 22(8): 895-898. doi: 10.1016/j.cclet.2011.01.033 shu

Amberlyst-15 catalyzed synthesis of alkyl/aryl/heterocyclic phosphonates

a Department of Chemistry, Sri Venkateswara University, Tirupati 517502, India;
b Bio-Organic Division, BARC, Mumbai, India

Received Date: 29 October 2010

A novel and efficient procedure for the synthesis of alkyl phosphonates through one pot condensation of alkyl halide and tri-alkyl/aryl phosphite in the presence of Amberlyst-15 as catalyst under solvent free conditions was applied. It demonstrated several advantages such as good yields of products, simple operation, convenient separation and inexpensive catalyst.
- An efficient magnesium bistrifluoromethanesulfonimide [Mg(NTf₂)₂] catalyzed hydroalkylation of aromatic olefins with 1,3-diketones under solvent-free conditions has been developed. The reactions proceed smoothly to give the desired products in good yields in short reaction times.
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