Citation: Xiu Juan Feng, Mei Yan, Xin Zhang, Ming Bao. Preparation and application of SBA-15-supported palladium catalyst for Heck reaction in supercritical carbon dioxide[J]. Chinese Chemical Letters, ;2011, 22(6): 643-646. doi: 10.1016/j.cclet.2010.12.044 shu

Preparation and application of SBA-15-supported palladium catalyst for Heck reaction in supercritical carbon dioxide

Xiu Juan Feng ^a, ,
Mei Yan ^a ,
Xin Zhang ^b ,
Ming Bao ^a

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China;
b School Environmental Science & Technology, Dalian University of Technology, Dalian 116023, China

Received Date: 9 December 2010

Fund Project: We are grateful to the National Natural Science Foundation of China (No.20603005) and the Specialized Research Fund for the Doctoral Program of Higher Education (No.20090041110012) for their financial support

A new method for the preparation of SB A-15-supported palladium catalyst for Heck reaction in supercritical carbon dioxide was presented.The newly formed SBA-15-supported palladium catalyst(Ph-SBA-15-PPh₃-Pd)exhibited high catalytic activity for the Heck reaction of 4-nitrobromobenzene with methyl acrylate.The catalyst can be reused several times without a loss of activity.
- SBA-15-supported palladium catalyst,
- Heck reaction,
- Supercritical carbon dioxide
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