Citation: Ateeq Rahman, S.M.Al Zahrani, Abdel Aziz Nait Ajjou. An efficient oxidation of benzylic and alicylic compounds with water-soluble copper catalysts in t-butyl hydroperoxide at room temperature[J]. Chinese Chemical Letters, ;2011, 22(6): 691-693. doi: 10.1016/j.cclet.2010.12.035 shu

An efficient oxidation of benzylic and alicylic compounds with water-soluble copper catalysts in t-butyl hydroperoxide at room temperature

a College of Engineering, Department of Chemical Engineering, King Saud University, Riaydh-11421, Saudi Arabia;
b Department of Chemistry and Biochemistry, University of Moncton, Moncton, New Brunswick, E1A3E9, Canada

Received Date: 10 September 2010

The water soluble catalytic system comprising of CuCl₂ and 2,2-biquinoline-4,4-dicarboxylic acid dipotassium salt(BQC)is highly efficient organic metallic catalysts for selective oxidation of benzylic and alicyclic compounds to the corresponding ketones, ex:indan to indanone, ethyl benzene to acetophenone.
- Oxidation,
- Bibenzyl,
- Allyl benzene,
- Indan,
- 2-Biquinoline-4,4-dicarboxylic acid dipotassium salt(BQC),
- Tetrabutyl ammonium bromide(TBAC)
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