引用本文:
Ze Zhang, Zhi Wei Peng, Kun Zeng Fan. Synthesis of polynorbornene with pendant moiety bearing azide and terminal alkyne groups[J]. Chinese Chemical Letters,
2011, 22(7): 785-788.
doi:
10.1016/j.cclet.2010.12.020
Citation: Ze Zhang, Zhi Wei Peng, Kun Zeng Fan. Synthesis of polynorbornene with pendant moiety bearing azide and terminal alkyne groups[J]. Chinese Chemical Letters, 2011, 22(7): 785-788. doi: 10.1016/j.cclet.2010.12.020
Citation: Ze Zhang, Zhi Wei Peng, Kun Zeng Fan. Synthesis of polynorbornene with pendant moiety bearing azide and terminal alkyne groups[J]. Chinese Chemical Letters, 2011, 22(7): 785-788. doi: 10.1016/j.cclet.2010.12.020
Synthesis of polynorbornene with pendant moiety bearing azide and terminal alkyne groups
摘要:
A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key intermediates, namely, 3-azido-5-(2-(trimethylsilyl)ethynyl) benzyl alcohol and 4-(4-aza-tricyclo [5.2.1.02.6]dec-8-en-4-yl) benzoic acid, were optimally synthesized for convergent synthesis of the corresponding monomer.
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关键词:
- Polynorbornene
- / Azide
- / Alkyne
- / Esterification
- / Metathesis
English
Synthesis of polynorbornene with pendant moiety bearing azide and terminal alkyne groups
Abstract:
A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key intermediates, namely, 3-azido-5-(2-(trimethylsilyl)ethynyl) benzyl alcohol and 4-(4-aza-tricyclo [5.2.1.02.6]dec-8-en-4-yl) benzoic acid, were optimally synthesized for convergent synthesis of the corresponding monomer.
-
Key words:
- Polynorbornene
- / Azide
- / Alkyne
- / Esterification
- / Metathesis
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