Citation: Ming Zhao, Chun Xiang Kuang, Xue Zhi Cheng, Qing Yang. Iron-catalyzed ketonization of 2-aryl-l,l-dibromoalkenes with KOAc:Synthesis of α-acetoxy aryl ketones via a Michael-like addition process[J]. Chinese Chemical Letters, ;2011, 22(5): 571-574. doi: 10.1016/j.cclet.2010.11.022 shu

Iron-catalyzed ketonization of 2-aryl-l,l-dibromoalkenes with KOAc:Synthesis of α-acetoxy aryl ketones via a Michael-like addition process

a Department of Chemistry, Tongji University, Shanghai 200092, China;
b Department of Biochemistry, School of Life Sciences, Fudan University, Shanghai 200433, China

Received Date: 14 September 2010

Fund Project: the Key Projects of Shanghai in Biomedical (No.08431902700) and the Scientific Research Foundation of State Education Ministry for the Returned Overseas Chinese Scholars.We would like to thank the Center for Instrumental Analysis, Tongji University, ChinaThe work was supported by Natural Science Foundation of China (No.30873153)

A novel and convenient iron-catalyzed ketonization of 2-aryl-1,1-dibromoalkenes with KOAc has been achieved.A series of α-acetoxy aryl ketones were prepared with moderate yields via 2-carbon position functionalization of 2-aryl-1,1-dibromoalkenes.
- Iron catalyst,
- Ketonization,
- Dibromoalkene,
- α-Acetoxy ketone,
- Potassium acetate
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