Citation: Min Zhu, Li Li, Jiang Ying Tong, Hui Zhang. An effective method for the preparation of chlorolactones[J]. Chinese Chemical Letters, ;2011, 22(4): 431-434. doi: 10.1016/j.cclet.2010.11.014 shu

An effective method for the preparation of chlorolactones

College of Biological and Environmental Sciences, Zhejiang Shuren University, Hangzhou 310015, China

Received Date: 23 August 2010

Fund Project: Financial support from the Zhejiang Province Natural Science Foundation of China (No. Y4080068) is greatly appreciated.

The effective chlorolactonization of alkenoic acids with (diacetoxyiodo)benzene and lithium chloride under mild conditions have been studied. Experiments show that various 4-pentenoic acids react with (diacetoxyiodo)benzene and lithium chloride fluently in CH₃OH at room temperature, obtaining five-membered chlorolactones in good yields in short times. Other alkenoic acids, such as 3-butenoic acid and trans 3-hexenoic acid give some more complicated results, and 4-pentynoic acid provides a chloroenol lactone with Z configuration in 40% of yield.
- Chlorolactone,
- (Diacetoxyiodo)benzene,
- Alkenoic acid,
- Preparation
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