引用本文:
Di Feng Wu, Mei Jia Yang, Yang Wang, Guo Wei Gao, Jian Men. A facile and efficient synthetic method for 4-phenylethynylphthalic anhydride[J]. Chinese Chemical Letters,
2011, 22(2): 159-162.
doi:
10.1016/j.cclet.2010.10.002
Citation: Di Feng Wu, Mei Jia Yang, Yang Wang, Guo Wei Gao, Jian Men. A facile and efficient synthetic method for 4-phenylethynylphthalic anhydride[J]. Chinese Chemical Letters, 2011, 22(2): 159-162. doi: 10.1016/j.cclet.2010.10.002
Citation: Di Feng Wu, Mei Jia Yang, Yang Wang, Guo Wei Gao, Jian Men. A facile and efficient synthetic method for 4-phenylethynylphthalic anhydride[J]. Chinese Chemical Letters, 2011, 22(2): 159-162. doi: 10.1016/j.cclet.2010.10.002
A facile and efficient synthetic method for 4-phenylethynylphthalic anhydride
摘要:
A novel approach to the synthesis of 4-phenylethynylphthalic anhydride has been described. The target compound was synthesized by Pd/Cu catalyzed Sonogashira coupling reaction between phenylacetylene and 4-bromophthalic acid which was for the first time employed as start material, followed by dehydration of 4-phenylethynylphthalic acid. Compared with traditional synthetic routes, this method provides several advantages such as readily available raw materials, convenient manipulation and high yield. The products were characterized by IR, 1H NMR, 13C NMR, MS and elemental analysis, respectively.
English
A facile and efficient synthetic method for 4-phenylethynylphthalic anhydride
Abstract:
A novel approach to the synthesis of 4-phenylethynylphthalic anhydride has been described. The target compound was synthesized by Pd/Cu catalyzed Sonogashira coupling reaction between phenylacetylene and 4-bromophthalic acid which was for the first time employed as start material, followed by dehydration of 4-phenylethynylphthalic acid. Compared with traditional synthetic routes, this method provides several advantages such as readily available raw materials, convenient manipulation and high yield. The products were characterized by IR, 1H NMR, 13C NMR, MS and elemental analysis, respectively.
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