Citation: Shu Shuang Li, An Feng Zhang, Min Liu, Xin Wen Guo. Synthesis and catalytic properties of hierarchical TS-1 in the presence of cationic organosilane surfactant[J]. Chinese Chemical Letters, ;2011, 22(3): 303-305. doi: 10.1016/j.cclet.2010.06.036 shu

Synthesis and catalytic properties of hierarchical TS-1 in the presence of cationic organosilane surfactant

State Key Lab of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

Received Date: 13 April 2010

Fund Project: This project was sponsored by program for new century excellent talents in university (No. NCET-04-0268) and "111"project.

Hierarchical TS-1 has been synthesized in the presence of cationic organosilane surfactant. The material is characterized with XRD, TEM, N₂ adsorption isotherm. The results show that the hierarchical TS-1 aggregates consist of small primary units with sizes of 20-30 nm. The BET surface area increases from 420 to 513 m²/g compared to conventional TS-1 zeolite. The sample is shown to be more active in epoxidation of cyclohexene than conventional TS-1.
- Cationic organosilane surfactant,
- Hierarchical TS-1,
- Cyclohexene
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