Citation: Liang Chun Wu, Long Qing Liu, Hai Shan Jin, Ming Liang Ma, Xiao Li Zhao, Ke Wen. Synthesis and structure determination of pyrazine-containing macrocyclic polyazomethines[J]. Chinese Chemical Letters, ;2010, 21(10): 1263-1266. doi: 10.1016/j.cclet.2010.05.017 shu

Synthesis and structure determination of pyrazine-containing macrocyclic polyazomethines

a Division of Supramolecular Chemistry and Medicinal Chemistry, Key Laboratory of Brain Functional Genomics, MOE, and Shanghai Key Laboratory of Brain Functional Genomics, East China Normal University, Shanghai 200062, China;
b Shanghai Key Laboratory of Green Chemistry and Chemical Processes, and Department of Chemistry, East China Normal University, Shanghai 200062, China

Received Date: 4 March 2010

Fund Project: The authors thank Shanghai Commission for Science and Technology (Nos.06Pj14034,06DZ19002,and 10ZR1409700),Ministry of Education (No.106078) for financial support.

Two pyrazine-containing macrocyclic polyazomethines 2 and 3 were synthesized by direct[2+2]and[3+3]condensation reactions between 2, 2'-[pyrazine-2, 3-diylbis(oxy)]dibenzaldehyde (1) and hydrazine. Both 2 and 3 were characterized by NMR, HRMS, and their structures were determined via X-ray crystal diffraction studies.
- Azomethine,
- Macrocycles,
- Schiff base,
- Pyrazine
1. [1]
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2. [2]
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3. [3]
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4. [4]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
  Conghui Wang , Lei Xu , Zhenhua Jia , Teck-Peng Loh . Recent applications of macrocycles in supramolecular catalysis. Chinese Chemical Letters, 2024, 35(4): 109075-. doi: 10.1016/j.cclet.2023.109075
14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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