引用本文:
Ming Ming Yu, Xia Li, Miao Luan, Jun Na Gao, Qiu Zhi Shi, Ming Sheng Tang, Liu He Wei. An improved synthesis of bis (cyclopentadienone)[J]. Chinese Chemical Letters,
2010, 21(10): 1157-1161.
doi:
10.1016/j.cclet.2010.04.005
Citation: Ming Ming Yu, Xia Li, Miao Luan, Jun Na Gao, Qiu Zhi Shi, Ming Sheng Tang, Liu He Wei. An improved synthesis of bis (cyclopentadienone)[J]. Chinese Chemical Letters, 2010, 21(10): 1157-1161. doi: 10.1016/j.cclet.2010.04.005
Citation: Ming Ming Yu, Xia Li, Miao Luan, Jun Na Gao, Qiu Zhi Shi, Ming Sheng Tang, Liu He Wei. An improved synthesis of bis (cyclopentadienone)[J]. Chinese Chemical Letters, 2010, 21(10): 1157-1161. doi: 10.1016/j.cclet.2010.04.005
An improved synthesis of bis (cyclopentadienone)
摘要:
An improved strategy for the synthesis of 3, 3'-(oxy-p-phenylene) bis (2, 4, 5-tdphenylcyclopentadienone) was developed, which includes three steps:Friedel-Crafts reaction, oxidation and condensation. Importantly, the use of KMnO4 made the second step simple and efficient, which has potential application to synthesis of bis (cyclopentadienone)s. The course of oxidation has been confirmed by isolated intermediates.
English
An improved synthesis of bis (cyclopentadienone)
Abstract:
An improved strategy for the synthesis of 3, 3'-(oxy-p-phenylene) bis (2, 4, 5-tdphenylcyclopentadienone) was developed, which includes three steps:Friedel-Crafts reaction, oxidation and condensation. Importantly, the use of KMnO4 made the second step simple and efficient, which has potential application to synthesis of bis (cyclopentadienone)s. The course of oxidation has been confirmed by isolated intermediates.
-
Key words:
- Bis (eyclopentadienone)
- / Friedel-Crafts reaction
- / Oxidation
- / Condensation
扫一扫看文章
计量
- PDF下载量: 2
- 文章访问数: 744
- HTML全文浏览量: 30
下载:
