引用本文:
Bo Wang, Jing He, Run Cang Sun. Carbamate synthesis from amines and dialkyl carbonate over inexpensive and clean acidic catalyst-Sulfamic acid[J]. Chinese Chemical Letters,
2010, 21(7): 794-797.
doi:
10.1016/j.cclet.2010.03.012
Citation: Bo Wang, Jing He, Run Cang Sun. Carbamate synthesis from amines and dialkyl carbonate over inexpensive and clean acidic catalyst-Sulfamic acid[J]. Chinese Chemical Letters, 2010, 21(7): 794-797. doi: 10.1016/j.cclet.2010.03.012
Citation: Bo Wang, Jing He, Run Cang Sun. Carbamate synthesis from amines and dialkyl carbonate over inexpensive and clean acidic catalyst-Sulfamic acid[J]. Chinese Chemical Letters, 2010, 21(7): 794-797. doi: 10.1016/j.cclet.2010.03.012
Carbamate synthesis from amines and dialkyl carbonate over inexpensive and clean acidic catalyst-Sulfamic acid
摘要:
Sulfamic acid has been proved to be the most efficient and recyclable catalyst in carbamate synthesis from alkylamine and dialkyl carbonate. High selectivity, cost-efficiency and simple product separation were the advantageous features obtained in this process. Sulfamic acid could be reused several times and keep its initial activity in the recycle runs. In addition, sulfamic acid has also exhibited the potential catalytic ability for alkylation of aromatic amines.
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关键词:
- Sulfamic acid
- / Acidic catalysis
- / Carbamate
- / Alkylamine
- / Dimethyl carbonate
English
Carbamate synthesis from amines and dialkyl carbonate over inexpensive and clean acidic catalyst-Sulfamic acid
Abstract:
Sulfamic acid has been proved to be the most efficient and recyclable catalyst in carbamate synthesis from alkylamine and dialkyl carbonate. High selectivity, cost-efficiency and simple product separation were the advantageous features obtained in this process. Sulfamic acid could be reused several times and keep its initial activity in the recycle runs. In addition, sulfamic acid has also exhibited the potential catalytic ability for alkylation of aromatic amines.
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Key words:
- Sulfamic acid
- / Acidic catalysis
- / Carbamate
- / Alkylamine
- / Dimethyl carbonate
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