Citation: Xin Yi Wang, Li Ping Heng, Nai Liang Yang, Qiang Xie, Jin Zhai. Preparation of polypyrrole/polyvinylalcohol (PPy/PVA)composite foam electrode material[J]. Chinese Chemical Letters, ;2010, 21(7): 884-887. doi: 10.1016/j.cclet.2010.01.005 shu

Preparation of polypyrrole/polyvinylalcohol (PPy/PVA)composite foam electrode material

Xin Yi Wang ^a,b, ,
Li Ping Heng ^b ,
Nai Liang Yang ^b ,
Qiang Xie ^a ,
Jin Zhai ^b,c

a School of Chemical and Environmental Engineering, China University of Mining & Technology, Beijing 100083, China;
b Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
c School of Chemistry and Environment, Beijing University of Aeronautics and Astronautics, Beijing 100081, China

Received Date: 23 October 2009

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 20773142, 50533030), the National Research Fund for Fundamental Key Project (No. 2006CB806200, 2006CB932100 and 2007CB936403) and 863 project (No. 2007AA032348 and 2008AA05Z308).

Polypyrrole/polyvinylalcohol (PPy/PVA) foam was prepared by direct foam polymerization in water and then it was coated on the indium-tin oxide transparent conductive glass (ITO) to form conventional three-electrode cell.FTIR and UV-vis spectra were adopted to characterize the molecular structure and the absorption spectra of foam material,respectively.The porous structure of PPy/PVA foams and their photoelectric conversion behaviors were studied.The dimension of the pores is bigger than 100 μm in diameter.Compared with the smooth film,the V_oc and I_sc of the foam film enhanced by 1.58-fold and 5.59-fold,respectively.
- Conjugated polymers,
- Foams,
- Photoelectric conversion,
- Polymerization
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4. [4]
  Yi Liu , Peng Lei , Yang Feng , Shiwei Fu , Xiaoqing Liu , Siqi Zhang , Bin Tu , Chen Chen , Yifan Li , Lei Wang , Qing-Dao Zeng . Topologically engineering of π-conjugated macrocycles: Tunable emission and photochemical reaction toward multi-cyclic polymers. Chinese Chemical Letters, 2024, 35(10): 109571-. doi: 10.1016/j.cclet.2024.109571
5. [5]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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14. [14]
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15. [15]
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16. [16]
  Hanying Li , Wee-Liat Ong . “Super-heterojunctioned” thermoelectric polymers. Chinese Chemical Letters, 2025, 36(2): 110523-. doi: 10.1016/j.cclet.2024.110523
17. [17]
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19. [19]
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