Citation: Heshmatollah Alinezhad, Mahmood Tajbakhsh, Neda Hamidi. Reductive animation of aldehydes and ketones using sodium borohydride in the presence of silica chloride under solvent-free conditions[J]. Chinese Chemical Letters, ;2010, 21(1): 47-50. doi: 10.1016/j.cclet.2009.07.018 shu

Reductive animation of aldehydes and ketones using sodium borohydride in the presence of silica chloride under solvent-free conditions

Faculty of Chemistry, Mazandaran University, Babolsar, Iran

Received Date: 18 May 2009

Fund Project: Financial support of this work from the Research Council of Mazandaran University gratefully acknowledged.

A simple and convenient procedure for the preparation of amines from aldehydes and ketones with sodium borohydride activated by silica chloride as a catalyst under solvent-free conditions is described. A variety of aliphatic and aromatic aldehydes, ketones and amines when mixed with NaBH₄/silica chloride at room temperature, afforded excellent yield of the corresponding amines.
- Reductive animation,
- Silica chloride,
- Solvent-free conditions,
- Sodium borohydride
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