Citation: S.Zarrabi, N.O.Mahmoodi K.Tabatabaeian, M.A.Zanjanchi. Baeyer-Villiger oxidation of cyclic ketones utilizing potassium peroxydisulfate (K₂S₂O₈) or sodium perborate (NaBO₃)in acidic media[J]. Chinese Chemical Letters, ;2009, 20(12): 1400-1404. doi: 10.1016/j.cclet.2009.07.007 shu

Baeyer-Villiger oxidation of cyclic ketones utilizing potassium peroxydisulfate (K₂S₂O₈) or sodium perborate (NaBO₃)in acidic media

Department of Chemistry, Faculty of Science, University of Guilan, Rasht, P.O.Box 1914, Iran

Received Date: 4 May 2009

The efficient, green, facile, mild and straightforward conversion procedure for the oxidation of cyclic ketones to lactones at room temperature utilizing potassium peroxydisulfate (K₂S ₂O₈) in acidic media is satisfactory to high yields without using traditional chlorinated solvents is reported.This oxidative reagent is cheap and friendly environmental procedure for industrial purposes than use of organic peracids.
- Baeyer-Villiger oxidation,
- Cyclic ketones,
- Potassium peroxydisulfate (K₂S₂₈),
- Acidic media,
- Sodium perborate (NaBO ₃)
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