Citation: Xu Zhang, Xin Guo, Li Ping Yang, Wen Hao Hu. Rh(Ⅱ) and Zn(Ⅱ) co-catalyzed multi-component reaction for the synthesis of vicinal diols[J]. Chinese Chemical Letters, ;2009, 20(11): 1299-1302. doi: 10.1016/j.cclet.2009.06.014 shu

Rh(Ⅱ) and Zn(Ⅱ) co-catalyzed multi-component reaction for the synthesis of vicinal diols

Xu Zhang ^a,b,c, ,
Xin Guo ^c ,
Li Ping Yang ^c ,
Wen Hao Hu ^c

a Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China;
b Graduate School of the Chinese Academy of Sciences, Beijing 100049, China;
c Department of Chemistry, East China Normal University, Shanghai 200062, China

Received Date: 19 March 2009

Fund Project: This work was supported by National Science Foundation of China (No. 20772033) and China postdoctoral Science Foundation (No. 20080440607).

Oxonium ylide intermediates generated from α-diazocarbonyl compounds and water were trapped by Zn(Ⅱ)-activated adicarbonyl compounds. The reaction gave α,β-dihydroxyl acid derivatives in moderate yield.
- Multi-component reaction,
- α-Diazocarbonyl compounds,
- Zn(OTf)₂,
- α-Dicarbonyl compounds
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