引用本文:
Cai Hua Zhou, Li Jun Zhou, Long Tang, Yao Yu Wang. Formation of infinite 2D water layers in a crystal host[J]. Chinese Chemical Letters,
2009, 20(7): 861-864.
doi:
10.1016/j.cclet.2009.03.030
Citation: Cai Hua Zhou, Li Jun Zhou, Long Tang, Yao Yu Wang. Formation of infinite 2D water layers in a crystal host[J]. Chinese Chemical Letters, 2009, 20(7): 861-864. doi: 10.1016/j.cclet.2009.03.030
Citation: Cai Hua Zhou, Li Jun Zhou, Long Tang, Yao Yu Wang. Formation of infinite 2D water layers in a crystal host[J]. Chinese Chemical Letters, 2009, 20(7): 861-864. doi: 10.1016/j.cclet.2009.03.030
Formation of infinite 2D water layers in a crystal host
摘要:
A self-assembled, (H2O)38 cluster stabilized by a mono-nuclear copper(Ⅱ) complex 1 namely {[Cu(phen)2(CO3)]·7H2O} is characterized by X-ray diffraction studies. The adjacent (H2O)38 clusters connect together resulting in an infinite 2D water layer structure. The water morphology is stable at room temperature, but upon thermal decomposition, the water loss is irreversible.
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关键词:
- Water cluster
- / Supramolecular
- / Hydrogen-bonding
English
Formation of infinite 2D water layers in a crystal host
Abstract:
A self-assembled, (H2O)38 cluster stabilized by a mono-nuclear copper(Ⅱ) complex 1 namely {[Cu(phen)2(CO3)]·7H2O} is characterized by X-ray diffraction studies. The adjacent (H2O)38 clusters connect together resulting in an infinite 2D water layer structure. The water morphology is stable at room temperature, but upon thermal decomposition, the water loss is irreversible.
-
Key words:
- Water cluster
- / Supramolecular
- / Hydrogen-bonding
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