Stereoselective cycloaddition of N-acyliminium cations with α,β-unsaturated ketones and esters

Ling Feng Qian ,  Yue Hua Zhou ,  Wei Zhang

引用本文: Ling Feng Qian,  Yue Hua Zhou,  Wei Zhang. Stereoselective cycloaddition of N-acyliminium cations with α,β-unsaturated ketones and esters[J]. Chinese Chemical Letters, 2009, 20(7): 805-808. doi: 10.1016/j.cclet.2009.03.006 shu
Citation:  Ling Feng Qian,  Yue Hua Zhou,  Wei Zhang. Stereoselective cycloaddition of N-acyliminium cations with α,β-unsaturated ketones and esters[J]. Chinese Chemical Letters, 2009, 20(7): 805-808. doi: 10.1016/j.cclet.2009.03.006 shu

Stereoselective cycloaddition of N-acyliminium cations with α,β-unsaturated ketones and esters

  • 基金项目:

    We thank the National Natural Science Foundation of China (No.20872056) for financial support.

摘要: The cycloaddition of N-acyliminium cations with some deactivated alkenes such as α,β-unsaturate ketones and esters has been investigated. In most cases, the N-acyliminium cations produced from 3-hydroxy-2-arylisoindol-1-ones in the presence of BF3·OEt2 could be reacted with α,β-unsaturated ketones and esters to afford stereoselectively the cycloaddition products 6-acylisoindolo[2,1-a] quinolin-11-ones in moderate to high yields.

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  • 收稿日期:  2008-12-03
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