Citation: Qiao Feng Wang, Xue Ying Liu, Xiang Yang Qin, Xiao Ye Li, Sheng Yong Zhang. One-pot-synthesis of novel cinchonine-based phosphites[J]. Chinese Chemical Letters, ;2009, 20(7): 797-799. doi: 10.1016/j.cclet.2009.02.015 shu

One-pot-synthesis of novel cinchonine-based phosphites

Department of Chemistry, Fourth Military Medical University, Xi'an 710032, China

Received Date: 18 November 2008

Fund Project: We are grateful to the National Natural Science Foundation of China (Nos. 20842007,30600163) and Natural Science Basic Research Plan in Shaanxi Province of China (No.SJ08-ZT02) for financial support.

Cinchonine was employed as backbone for the synthesis of novel phosphite compounds with diol substituents. These monophosphinites were provided in one pot with the yields ranged from 63% to 75%. Their structures were confirmed byNMR spectroscopy and HRMS.
- Cinchona alkaloids,
- Diols,
- Chiral phosphite,
- Asymmetric reaction,
- Ligand
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