Citation:
Arash Ghorbani-Choghamarani, Hamid Goudarziafshar, Somaieh Rezaee, Saiedeh Shima Mortazavi. Chemoselective N-nitrosation of secondary amines under heterogeneous and mild conditions via in situ generation of HNO2[J]. Chinese Chemical Letters,
;2009, 20(4): 415-419.
doi:
10.1016/j.cclet.2008.12.044
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A wide variety of secondary amines are chemoselectively subjected to N-nitrosation reaction with treatment of citric acid and NaNO2 in the presence of wet SiO2 (50%, w/w) in dichloromethane at room temperatture under heterogeneous conditions. The N-nitrosation method is very simple and products can be easily isolated with good to high yields.
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Keywords:
- N-Nitrosation,
- Secondary amines,
- Heterogeneous,
- Citric acid,
- NaNO2
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