Citation:
Hui Zhen Zhi, Jun Luo, Guang An Feng, Chun Xu Lv. An efficient method to synthesize HMX by nitrolysis of DPT with N2O5 and a novel ionic liquid[J]. Chinese Chemical Letters,
;2009, 20(4): 379-382.
doi:
10.1016/j.cclet.2008.12.040
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A novel polyethylene glycol (PEG)-200-based dicationic acidic ionic liquid (PEG200-DAIL) was used to synthesize HMX from DPT by nitrolysis with N2O5. It was found that either N2O5 or PEG200-DAIL could improve the yield. Furthermore, the combined use of PEG200-DAIL and N2O5 could increase the yield of HMX to 64% with the used quantity of HNO3 decreased dramatically.
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Keywords:
- DPT,
- Nitrolysis,
- N2O5,
- Acidic ionic liquid
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