Citation: Mohammad Reza Bozorgmehr, Mohammad Reza Housaindokht. Evaluation of attraction terms in equations of state on the prediction of solubility of some biomolecules in supercritical carbon dioxide[J]. Chinese Chemical Letters, ;2009, 20(4): 501-505. doi: 10.1016/j.cclet.2008.12.020 shu

Evaluation of attraction terms in equations of state on the prediction of solubility of some biomolecules in supercritical carbon dioxide

Mohammad Reza Bozorgmehr ^a ,
Mohammad Reza Housaindokht ^b

a Department of Chemistry, Faculty of Science, Islamic Azad University, Mashad Branch, Mashhad, Iran;
b Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashad, Iran Received 22 September 2008

Received Date: 22 September 2008

In the present work, effect of the attraction terms of four recently modified Peng-Robinson equations of state on the prediction of solubility of caffeine, cholesterol, uracil and erythromycin was studied. The attraction terms of two of these equations are linear relative to the acentric factor and for the other two are exponential. It is found that the later show less deviation. Also interaction parameters for the studied systems are obtained and the percentage of average absolute relative deviation (%AARD) in each calculation is displayed.
- Equation of state,
- Solubility,
- Supercritical carbon dioxide,
- Biomolecules
1. [1]
  Qi Long REN , Mci HUANG , Bao Gen SU , Ping Dong WU . Enhancement of Solubility of Troeger's Base in Supercritical Carbon Dioxide by Methanol. Chinese Chemical Letters, 2000, 11(9): 823-826.
2. [2]
  Shou Gang WANG , Hong Wei XIANG , Bu Xing HAN . A New Perturbed Hard-Sphere Equation of State. Chinese Chemical Letters, 2000, 11(11): 989-992.
3. [3]
  Guo Chen YANG , Hai Jian YANG . Metal Ions Extraction with Glucose Derivatives as Chelating Reagents in Supercritical Carbon Dioxide. Chinese Chemical Letters, 2006, 17(11): 1489-1492.
4. [4]
  Behzad Haghighi , Mohammad Reza Hussaindokht , Mohammad Reza Bozorgmehr , Naser Seyed Matin . Joule-Thomson inversion curve prediction by using equation of state. Chinese Chemical Letters, 2007, 18(9): 1154-1158. doi: 10.1016/j.cclet.2007.07.002
5. [5]
  Chun Sheng Li , Jing Cui Liang , Xiao Li Zhu , Xiang Zheng Kong . Effects of cosolvent on formation and morphology of microspheres in precipitation polymerization of divinylbenzene in supercritical carbon dioxide. Chinese Chemical Letters, 2011, 22(4): 489-492. doi: 10.1016/j.cclet.2010.10.022
6. [6]
  Xiao Bing LU , Yu Zhen PAN , Dong Feng JI , Ren HE . Catalytic Formation of Propylene Carbonate from Supercritical Carbon Dioxide/Propylene Oxide Mixture. Chinese Chemical Letters, 2000, 11(7): 589-592.
7. [7]
  Xiu Juan Feng , Mei Yan , Xin Zhang , Ming Bao . Preparation and application of SBA-15-supported palladium catalyst for Heck reaction in supercritical carbon dioxide. Chinese Chemical Letters, 2011, 22(6): 643-646. doi: 10.1016/j.cclet.2010.12.044
8. [8]
  Jun Cheng LIU , Jian Ling ZHANG , Bu Xing HAN , Gan Zuo LI , Guan Ying YANG . Study on the Phase Behavior of Supercritical CO₂/Dynol-604/Water System and Solubilization of Methyl Orange in the Microemulsions. Chinese Chemical Letters, 2002, 13(1): 87-90.
9. [9]
  Ali Niazi , Saeed Jameh-Bozorghi , Davood Nori-Shargh . Quantitative structure-property relationship study of the solubility of thiazolidine-4-carboxylic acid derivatives using ab initio and genetic algorithm-partial least squares. Chinese Chemical Letters, 2007, 18(5): 621-624. doi: 10.1016/j.cclet.2007.02.017
10. [10]
  Xin Qiu , Li Chuan Tang , Chao Qing Dong , Ji Cun Ren . Characterization of gold nanoparticle bioconjugation by resonance light scattering correlation spectroscopy. Chinese Chemical Letters, 2010, 21(10): 1227-1230. doi: 10.1016/j.cclet.2010.05.007
11. [11]
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12. [12]
  Li Hong Xiao , Cheng Liu , Xi Gao Jian . Synthesis and characterization of novel poly(aryl ether sulfone ketone)s containing phthalazinone and biphenyl moieties. Chinese Chemical Letters, 2008, 19(2): 227-229. doi: 10.1016/j.cclet.2007.11.005
13. [13]
  Ming Jing Wang , Cheng Liu , Li Ming Dong , Xi Gao Jian . Synthesis and characterization of new soluble poly(aryl ether nitrile)s containing phthalazinone moiety. Chinese Chemical Letters, 2007, 18(5): 595-597. doi: 10.1016/j.cclet.2007.03.030
14. [14]
  Meng Fan-Qiang , Feng Xiu-Juan , Wang Wan-Hui , Bao Ming . Synthesis of 5-vinyl-2-norbornene through Diels-Alder reaction of cyclopentadiene with 1, 3-butadiene in supercritical carbon dioxide. Chinese Chemical Letters, 2017, 28(4): 900-904. doi: 10.1016/j.cclet.2016.12.018
15. [15]
  Yun Xia Wei , Ming Guang Ma , Guo Hu Zhao , Sheng Ying Li , Ming Kai Chen . Synthesis of a new aromatic dianhydride monomer and related polyimide. Chinese Chemical Letters, 2009, 20(2): 229-230. doi: 10.1016/j.cclet.2008.10.031
16. [16]
  Yu Shao , Yan Feng Li , Xiao Long Wang , Jin Shan Guo , Xin Zhao . Synthesis of a new siloxane-containing diamine and related polyimide. Chinese Chemical Letters, 2007, 18(6): 762-763. doi: 10.1016/j.cclet.2007.03.009
17. [17]
  Li Yaohao , Clark Kimberly A. , Tan Zhongping . Methods for engineering therapeutic peptides. Chinese Chemical Letters, 2018, 29(7): 1074-1078. doi: 10.1016/j.cclet.2018.05.027

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