Citation:
Yong Qiang Ma, Ning Yin, Wen Jing Peng, Jing Li. Reactions and crystal structures of heterodinuclear complexes R3Sn-M(CO)5 (M=Mn, Re) with some nitrogen ligands[J]. Chinese Chemical Letters,
;2009, 20(4): 465-468.
doi:
10.1016/j.cclet.2008.12.017
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Some reactions of R3SnM(CO)5 (M=Mn, Re) with CH3CN or pyridine were investigated to give complexes R3SnMn(CO)3LL'or R3SnMn(CO)4L by a facile mild method. X-ray diffractions analyses show that, in contrast to the phosphine ligand occupying in axial position, nitrogen ligands occupy equatorial position.
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Keywords:
- Reactions,
- Heterodinuclear complexes,
- X-ray structure
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