Citation: Yong Qiang Ma, Ning Yin, Wen Jing Peng, Jing Li. Reactions and crystal structures of heterodinuclear complexes R₃Sn-M(CO)₅ (M=Mn, Re) with some nitrogen ligands[J]. Chinese Chemical Letters, ;2009, 20(4): 465-468. doi: 10.1016/j.cclet.2008.12.017 shu

Reactions and crystal structures of heterodinuclear complexes R₃Sn-M(CO)₅ (M=Mn, Re) with some nitrogen ligands

a Department of Applied Chemistry, China Agriculture University, Beijing 100193, China;
b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

Received Date: 8 September 2008

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 29672018).

Some reactions of R₃SnM(CO)₅ (M=Mn, Re) with CH₃CN or pyridine were investigated to give complexes R₃SnMn(CO)₃LL'or R₃SnMn(CO)₄L by a facile mild method. X-ray diffractions analyses show that, in contrast to the phosphine ligand occupying in axial position, nitrogen ligands occupy equatorial position.
- Reactions,
- Heterodinuclear complexes,
- X-ray structure
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