Citation: Long Shen, Yu Cao, Chang Wen Hu. Synthesis and structure of a new 1D infinite neutral chain based on organotin and selenious acid monoethyl ester[J]. Chinese Chemical Letters, ;2009, 20(3): 370-373. doi: 10.1016/j.cclet.2008.12.010 shu

Synthesis and structure of a new 1D infinite neutral chain based on organotin and selenious acid monoethyl ester

Department of Chemistry, Institute for Chemical Physics and State Key Laboratory of Explosion Science Technology, Beijing Institute of Technology, Beijing 100081, P. R. China

Received Date: 28 August 2008

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 20671011, 20731002), the 111 Project (No. B07012), Key Laboratory of Structural Chemistry Foundation (No. 060017), Excellent Young Scholars Research Fund of Beijing Institute of Technology (No. 2006Y0715) and Basic Research Fund of Beijing Institute of Technology (Nos. 20060742022, 20070742010).

A new 1D infinite neutral chain (Ph₃SnO₂SeOCH₂CH₃)_n (1) based on organotin and selenious acid monoethyl ester has been synthesized successfully and characterized by IR, elemental analysis, and X-ray single-crystal diffraction. In the compound 1, the Sn atom exists in slightly distorted trigonal bipyramidal geometry and the Se center is tri-coordinated with a distorted pyramidal arrangement. It is noted that the synthesis is facile and selenium oxide is directly introduced into synthesis route replacing organoseleninic acid under room temperature.
- Organotin,
- Selenium oxide,
- Crystal structure
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