Citation: Yu Fen LÜ, Liang Fang Zhu, Qiu Yuan Liu, Bin Guo, Xiao Ke Hu, Chang Wei Hu. Direct amination of benzene to aniline with several typical vanadium complexes[J]. Chinese Chemical Letters, ;2009, 20(2): 238-240. doi: 10.1016/j.cclet.2008.11.005 shu

Direct amination of benzene to aniline with several typical vanadium complexes

Key Laboratory of Green Chemistry and Technology (Sichuan University), Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, PR China

Received Date: 28 August 2008

Fund Project: The project is supported by the National Natural Science Foundation of China (No. 200720024).

The liquid-phase direct catalytic amination of benzene to aniline was performed in acetic acid water solvent using a series of vanadium (Ⅲ, Ⅳ, Ⅴ) complexes with N,O-or O,O-ligands as catalysts and hydroxylamine hydrochloride as the aminating agent.The vanadium complexes exhibited much higher selectivity towards the production of aniline than NaVO₃ or VOSO₄. Under the optimized conditions, an aniline yield of 42.5% and a TON of 48 with a high selectivity of above 99.9% was obtained using 0.2 mmol of [VO(OAc)₂] as the catalyst.
- Amination,
- Benzene,
- Hydroxylamine,
- Vanadium complexes
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