引用本文:
Xiao Ning Wei, Ling Yan Liu, Bing Wang, Wei Xing Chang, Jing Li. In(OTf)3 catalyzed allylation reaction of imines with tetraallyltin[J]. Chinese Chemical Letters,
2009, 20(1): 40-43.
doi:
10.1016/j.cclet.2008.10.013
Citation: Xiao Ning Wei, Ling Yan Liu, Bing Wang, Wei Xing Chang, Jing Li. In(OTf)3 catalyzed allylation reaction of imines with tetraallyltin[J]. Chinese Chemical Letters, 2009, 20(1): 40-43. doi: 10.1016/j.cclet.2008.10.013
Citation: Xiao Ning Wei, Ling Yan Liu, Bing Wang, Wei Xing Chang, Jing Li. In(OTf)3 catalyzed allylation reaction of imines with tetraallyltin[J]. Chinese Chemical Letters, 2009, 20(1): 40-43. doi: 10.1016/j.cclet.2008.10.013
In(OTf)3 catalyzed allylation reaction of imines with tetraallyltin
摘要:
In the presence of catalytic amount of In(OTf)3 (10 mol%), a series of aldimines reacted with tetraallyltin in a 2:1 molar ratio to afford the corresponding homoallylic amines in good yields. The good atom efficiency was achieved under mild reaction conditions and a new protocol (allyl)4Sn/In(OTf)3 for simple imines was developed.
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关键词:
- Catalytic allylation
- / Aldimine
- / Tetraallyltin
- / In(OTf)3
English
In(OTf)3 catalyzed allylation reaction of imines with tetraallyltin
Abstract:
In the presence of catalytic amount of In(OTf)3 (10 mol%), a series of aldimines reacted with tetraallyltin in a 2:1 molar ratio to afford the corresponding homoallylic amines in good yields. The good atom efficiency was achieved under mild reaction conditions and a new protocol (allyl)4Sn/In(OTf)3 for simple imines was developed.
-
Key words:
- Catalytic allylation
- / Aldimine
- / Tetraallyltin
- / In(OTf)3
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