引用本文:
Dong Xia Zhao, Zhen Zhen Xu, Zhong Zhi Yang. Theoretical investigation of the stereoselectivity of some Diels-Alder reactions involving cyclopentadiene[J]. Chinese Chemical Letters,
2008, 19(9): 1135-1138.
doi:
10.1016/j.cclet.2008.06.023
Citation: Dong Xia Zhao, Zhen Zhen Xu, Zhong Zhi Yang. Theoretical investigation of the stereoselectivity of some Diels-Alder reactions involving cyclopentadiene[J]. Chinese Chemical Letters, 2008, 19(9): 1135-1138. doi: 10.1016/j.cclet.2008.06.023
Citation: Dong Xia Zhao, Zhen Zhen Xu, Zhong Zhi Yang. Theoretical investigation of the stereoselectivity of some Diels-Alder reactions involving cyclopentadiene[J]. Chinese Chemical Letters, 2008, 19(9): 1135-1138. doi: 10.1016/j.cclet.2008.06.023
Theoretical investigation of the stereoselectivity of some Diels-Alder reactions involving cyclopentadiene
摘要:
The stereoselectivity of some Diels-Alder reactions was investigated by means of ABEEM-Óπ model. Combined with local hard-soft and acid-base (HSAB) principle, we made reasonable explanation by calculating local softness of atom and bond regions for the stereoselectivity of four Diels-Alder reactions involving cyclopentadiene.
English
Theoretical investigation of the stereoselectivity of some Diels-Alder reactions involving cyclopentadiene
Abstract:
The stereoselectivity of some Diels-Alder reactions was investigated by means of ABEEM-Óπ model. Combined with local hard-soft and acid-base (HSAB) principle, we made reasonable explanation by calculating local softness of atom and bond regions for the stereoselectivity of four Diels-Alder reactions involving cyclopentadiene.
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Key words:
- ABEEM-Óπ model
- / Diels-Alder reaction
- / Stereoselecfivity
- / Local softness
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