引用本文:
Sheng Zu Zhang, Xin Jian Fu, Hong Wang, Ya Jiang Yang. Mechanism of N-octadecyl-N'-maleoyl-L-phenylalanine self-assembled into supramolecular structures[J]. Chinese Chemical Letters,
2008, 19(9): 1119-1122.
doi:
10.1016/j.cclet.2008.06.011
Citation: Sheng Zu Zhang, Xin Jian Fu, Hong Wang, Ya Jiang Yang. Mechanism of N-octadecyl-N'-maleoyl-L-phenylalanine self-assembled into supramolecular structures[J]. Chinese Chemical Letters, 2008, 19(9): 1119-1122. doi: 10.1016/j.cclet.2008.06.011
Citation: Sheng Zu Zhang, Xin Jian Fu, Hong Wang, Ya Jiang Yang. Mechanism of N-octadecyl-N'-maleoyl-L-phenylalanine self-assembled into supramolecular structures[J]. Chinese Chemical Letters, 2008, 19(9): 1119-1122. doi: 10.1016/j.cclet.2008.06.011
Mechanism of N-octadecyl-N'-maleoyl-L-phenylalanine self-assembled into supramolecular structures
摘要:
N-Octadecyl-N'-maleoyl-L-phenylalanine (ODMA-L-Phe) was synthesized through the condensation, deprotection and aeid-ylation reaction of BOC-L-phenylalanine, octadecylamine and maleic anhydride. ODMA-L-Phe can self-assemble in some organic solvents and turned them into thermally reversible physical supramolecular organogels. The morphology of ODMA-L-Phe aggregates was characterized by polarized optical microscopy (POM) and field emission scanning electron microscope (FE-SEM). The aggregates of ODMA-L-Phe were needle-like fibrils with diameters of approximately 100-200 nm. The mechanism of ODMA-L-Phe self-assembly in organic solvents was investigated using 1H NMR and circular dichroism (CD). The results indicated that hydrogen bonding was one of the main driving forces for the self-assembly of ODMA-L-Phe.
English
Mechanism of N-octadecyl-N'-maleoyl-L-phenylalanine self-assembled into supramolecular structures
Abstract:
N-Octadecyl-N'-maleoyl-L-phenylalanine (ODMA-L-Phe) was synthesized through the condensation, deprotection and aeid-ylation reaction of BOC-L-phenylalanine, octadecylamine and maleic anhydride. ODMA-L-Phe can self-assemble in some organic solvents and turned them into thermally reversible physical supramolecular organogels. The morphology of ODMA-L-Phe aggregates was characterized by polarized optical microscopy (POM) and field emission scanning electron microscope (FE-SEM). The aggregates of ODMA-L-Phe were needle-like fibrils with diameters of approximately 100-200 nm. The mechanism of ODMA-L-Phe self-assembly in organic solvents was investigated using 1H NMR and circular dichroism (CD). The results indicated that hydrogen bonding was one of the main driving forces for the self-assembly of ODMA-L-Phe.
-
Key words:
- Gelator
- / Self-assembly
- / Supramolecular structures
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 684
- HTML全文浏览量: 0
下载:
