Palladium-catalyzed highly regioselective Heck reaction of aryl nonaflates with electron-rich olefins

Dan Xu Zhi Hua Liu Wei Jun Tang Jun Mo Li Jin Xu

引用本文: Dan Xu,  Zhi Hua Liu,  Wei Jun Tang,  Jun Mo,  Li Jin Xu. Palladium-catalyzed highly regioselective Heck reaction of aryl nonaflates with electron-rich olefins[J]. Chinese Chemical Letters, 2008, 19(9): 1017-1020. doi: 10.1016/j.cclet.2008.06.004 shu
Citation:  Dan Xu,  Zhi Hua Liu,  Wei Jun Tang,  Jun Mo,  Li Jin Xu. Palladium-catalyzed highly regioselective Heck reaction of aryl nonaflates with electron-rich olefins[J]. Chinese Chemical Letters, 2008, 19(9): 1017-1020. doi: 10.1016/j.cclet.2008.06.004 shu

Palladium-catalyzed highly regioselective Heck reaction of aryl nonaflates with electron-rich olefins

  • 基金项目:

    We thank the Renmin University of China and the National Natural Science Foundation of China (Nos. 20542009 and 20672139) for financial support.

摘要: Highly efficient palladium-catalyzed Heck coupling of aryl nonaflates with electron-rich vinyl ethers, and enamides is described. These reactions afforded exclusively the branched products in good yields. The results indicated that aryl nonaflates are effective alternative to the frequently employed aryl triflates.

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  • 收稿日期:  2008-01-23
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