Citation: Ya Ping Xu, Rong Hua Hu, Ming Zhong Cai. A facile synthesis of terminal arylacetylenes via Sonogashira coupling reactions catalyzed by MCM-41-supported mercapto palladium(0) complex[J]. Chinese Chemical Letters, ;2008, 19(7): 783-787. doi: 10.1016/j.cclet.2008.05.016 shu

A facile synthesis of terminal arylacetylenes via Sonogashira coupling reactions catalyzed by MCM-41-supported mercapto palladium(0) complex

a Department of Chemistry, Jiangxi Normal University, Nanchang 330022, China;
b Department of Chemistry, Jinggangshan University, Jian 343009, China

Received Date: 11 January 2008

Fund Project: We thank the National Natural Science Foundation of China (No.20462002) and Natural Science Foundation of Jiangxi Province (No.0420015) for financial support

A variety of terminal arylacetylenes have been conveniently synthesized in good to high yields via Sonogashira coupling of aryl iodides with (trimethylsilyl)acetylene catalyzed by MCM-41-supported mercapto palladium(0) complex,followed by desilylation under mild conditions.This polymeric palladium catalyst can be reused many times without any decrease in activity.
- Sonogashira coupling,
- MCM-41-supported catalyst,
- Mercapto palladium(0) complex,
- Terminal arylacetylene,
- Heterogeneous catalysis
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