Citation: Xiao Ping Chen, Zhi Ming Zhou, Hao Yuan, Zi Hui Meng. Preparation and chiral recognition of a novel chiral stationary phase for HPLC,based on mono(6^A-N-1-(2-hydroxyl)-phenylethylimino-6^A-deoxy)-β-cyclodextrin and covalently bonded silica gel[J]. Chinese Chemical Letters, ;2008, 19(7): 797-800. doi: 10.1016/j.cclet.2008.04.045 shu

Preparation and chiral recognition of a novel chiral stationary phase for HPLC,based on mono(6^A-N-1-(2-hydroxyl)-phenylethylimino-6^A-deoxy)-β-cyclodextrin and covalently bonded silica gel

School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing[4_TD$DIF] 100081, China

Received Date: 25 February 2008

Fund Project: Financial support from the National Natural Science Foundation of China (No.20572009) is gratefully acknowledged.

A novel chiral stationary phase (CSP) was prepared by immobilizing mono(6^A-N-1-(2-hydroxyl)-phenylethylimino-6^A-deoxy)-β-cyclodextrin onto the surface of silica gel via a longer spacer.This chiral stationary phase exhibited good enantios electivity for a variety of chiral compounds under reversed-phase conditions.
- Cyclodextrin,
- Enantioseparation,
- Chirai stationary phase,
- Ferrocene derivatives
1. [1]
  Linnan Jiang , Zhenkai Qian , Yong Chen , Xiaoyong Yu , Yugui Qiu , Wen-Wen Xu , Yonghui Sun , Xiufang Xu , Lihua Wang , Yu Liu . Double response reversible phosphorescence based on cyclodextrin supramolecular flexible elastic achieved multicolor delayed fluorescence. Chinese Chemical Letters, 2025, 36(8): 110676-. doi: 10.1016/j.cclet.2024.110676
2. [2]
  Yu-Hui Zhang , Ye Tian , Xianliang Sheng , Chen-Shuang Liu , Lu-Qiang Wei , Jie Wang , Yong Chen . Construction of a black phosphorous-based noncovalent multiple nanosupramolecular assembly for synergistic targeted photothermal and chemodynamic therapy. Chinese Chemical Letters, 2025, 36(4): 110193-. doi: 10.1016/j.cclet.2024.110193
3. [3]
  Genlin Sun , Yachun Luo , Zhihong Yan , Hongdeng Qiu , Weiyang Tang . Chiral metal-organic frameworks-based materials for chromatographic enantioseparation. Chinese Chemical Letters, 2024, 35(12): 109787-. doi: 10.1016/j.cclet.2024.109787
4. [4]
  Qinwei Lu , Jinjie Lu , Juying Lei , Xubiao Luo , Yanbo Zhou . Cyclodextrin-boosted photocatalytic oxidation for efficient bisphenol A removal. Chinese Chemical Letters, 2025, 36(3): 110017-. doi: 10.1016/j.cclet.2024.110017
5. [5]
  Wangyan Hu , Ke Li , Xiangnan Dou , Ning Li , Xiayan Wang . Nano-sized stationary phase packings retained by single-particle frit for microchip liquid chromatography. Chinese Chemical Letters, 2024, 35(4): 108806-. doi: 10.1016/j.cclet.2023.108806
6. [6]
  Tong Zhang , Xiaojing Liang , Licheng Wang , Shuai Wang , Xiaoxiao Liu , Yong Guo . An ionic liquid assisted hydrogel functionalized silica stationary phase for mixed-mode liquid chromatography. Chinese Chemical Letters, 2025, 36(1): 109889-. doi: 10.1016/j.cclet.2024.109889
7. [7]
  Siwei Wang , Wei-Lei Zhou , Yong Chen . Cucurbituril and cyclodextrin co-confinement-based multilevel assembly for single-molecule phosphorescence resonance energy transfer behavior. Chinese Chemical Letters, 2024, 35(12): 110261-. doi: 10.1016/j.cclet.2024.110261
8. [8]
  Wenjia Wang , Xingyue He , Xiaojie Wang , Tiantian Zhao , Osamu Muraoka , Genzoh Tanabe , Weijia Xie , Tianjiao Zhou , Lei Xing , Qingri Jin , Hulin Jiang . Glutathione-depleted cyclodextrin pseudo-polyrotaxane nanoparticles for anti-inflammatory oxaliplatin (Ⅳ) prodrug delivery and enhanced colorectal cancer therapy. Chinese Chemical Letters, 2024, 35(4): 108656-. doi: 10.1016/j.cclet.2023.108656
9. [9]
  Chun-Ying Xu , Xiao-Lin Luan , Yuan-Yuan Cui , Cheng-Xiong Yang . One-pot in situ doping synthesis of phenylboronic acid-functionalized magnetic-cyclodextrin microporous organic network for specific enrichment and detection of sulfonylurea herbicides. Chinese Chemical Letters, 2025, 36(9): 110937-. doi: 10.1016/j.cclet.2025.110937
10. [10]
  Lina Xie , Xiaohe Zhang , Xiaobo Wang , Zhen Zhang , Tianqi Nie , Jun Wu , Xiaojun Xu . Multifunctional GelMA hydrogel doped with spermidine-ferrocene polymeric nanoparticles for accelerative diabetic wound healing. Chinese Chemical Letters, 2025, 36(11): 110848-. doi: 10.1016/j.cclet.2025.110848
11. [11]
  Ping Sun , Yuanqin Huang , Shunhong Chen , Xining Ma , Zhaokai Yang , Jian Wu . Indole derivatives as agrochemicals: An overview. Chinese Chemical Letters, 2024, 35(7): 109005-. doi: 10.1016/j.cclet.2023.109005
12. [12]
  Fangwen Peng , Zhen Luo , Yingjin Ma , Haibo Ma . Theoretical study of aromaticity reversal in dimethyldihydropyrene derivatives. Chinese Journal of Structural Chemistry, 2024, 43(5): 100273-100273. doi: 10.1016/j.cjsc.2024.100273
13. [13]
  Tingting Du , Siyu Lu , Zongnan Zhu , Mei Zhu , Yan Zhang , Jian Zhang , Jixiang Chen . Pyrazole derivatives: Recent advances in discovery and development of pesticides. Chinese Chemical Letters, 2025, 36(9): 110912-. doi: 10.1016/j.cclet.2025.110912
14. [14]
  Wenyi Mei , Lijuan Xie , Xiaodong Zhang , Cunjian Shi , Fengzhi Wang , Qiqi Fu , Zhenjiang Zhao , Honglin Li , Yufang Xu , Zhuo Chen . Design, synthesis and biological evaluation of fluorescent derivatives of ursolic acid in living cells. Chinese Chemical Letters, 2024, 35(5): 108825-. doi: 10.1016/j.cclet.2023.108825
15. [15]
  Yadan SUN , Xinfeng LI , Qiang LIU , Oshio Hiroki , Yinshan MENG . Structures and magnetism of dinuclear Co complexes based on imine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2212-2220. doi: 10.11862/CJIC.20240131
16. [16]
  Zhuwen Wei , Jiayan Chen , Congzhen Xie , Yang Chen , Shifa Zhu . Divergent de novo construction of α-functionalized pyrrole derivatives via coarctate reaction. Chinese Chemical Letters, 2024, 35(12): 109677-. doi: 10.1016/j.cclet.2024.109677
17. [17]
  Fei-Yan Gao , Yan Wu , Ling Yang , Zhong-Yi Ma , Yi Chen , Xiao-Man Mao , Xu-Fei Bian , Pei Tang , Chong Li . Orally delivered berberine derivatives for dual therapy in diabetic complications with MRSA infections. Chinese Chemical Letters, 2025, 36(4): 109917-. doi: 10.1016/j.cclet.2024.109917
18. [18]
  Junlong Tang , Yuhan Zhao , Yangbin Jin , Liren Zhang , Yuanfang Wang , Wanqing Wu , Huanfeng Jiang . Palladium-catalyzed modular biomimetic synthesis of lignans derivatives. Chinese Chemical Letters, 2025, 36(7): 110969-. doi: 10.1016/j.cclet.2025.110969
19. [19]
  Guodong Wang , Mengying Jia , Haitao Liu , Yong Liu , Zhiguo Zhang , Xianxiu Xu . Expeditious synthesis and applications of isoquinoline ring-modified Quinap derivatives. Chinese Chemical Letters, 2025, 36(8): 110705-. doi: 10.1016/j.cclet.2024.110705
20. [20]
  Sha-Sha Meng , Xiao-Yi Fu , Hai-Yue Wei , Ming Xu , Zhi-Yuan Gu . Improving the separation ability of MOF-based stationary phases by increasing the thermodynamic differentiation of analytes. Chinese Chemical Letters, 2025, 36(9): 110720-. doi: 10.1016/j.cclet.2024.110720