引用本文:
Yan Ping Wang, Wen Fa Xie, Bin Li, Wen Lian Li. Synthesis,characterization,photoluminescence and electroluminescence properties of new 1,3,4-oxadiazole-containing rhenium (Ⅰ) complex Re (CO)3 (Bphen)(PTOP)[J]. Chinese Chemical Letters,
2007, 18(12): 1501-1504.
doi:
10.1016/j.cclet.2007.10.003
Citation: Yan Ping Wang, Wen Fa Xie, Bin Li, Wen Lian Li. Synthesis,characterization,photoluminescence and electroluminescence properties of new 1,3,4-oxadiazole-containing rhenium (Ⅰ) complex Re (CO)3 (Bphen)(PTOP)[J]. Chinese Chemical Letters, 2007, 18(12): 1501-1504. doi: 10.1016/j.cclet.2007.10.003
Citation: Yan Ping Wang, Wen Fa Xie, Bin Li, Wen Lian Li. Synthesis,characterization,photoluminescence and electroluminescence properties of new 1,3,4-oxadiazole-containing rhenium (Ⅰ) complex Re (CO)3 (Bphen)(PTOP)[J]. Chinese Chemical Letters, 2007, 18(12): 1501-1504. doi: 10.1016/j.cclet.2007.10.003
Synthesis,characterization,photoluminescence and electroluminescence properties of new 1,3,4-oxadiazole-containing rhenium (Ⅰ) complex Re (CO)3 (Bphen)(PTOP)
摘要:
A new 1, 3, 4-oxadiazole-contanining rhenium (Ⅰ) complex, with the formula[Re (CO)3 (Bphen)(PTOP)], (Bphen=bathophenardine, PTOP=4-(5-p-tolyl-1, 3, 4-oxadiazd-2-yl) pyridine), is synthesized and characterized by elemental analysis, IR, 1H NMR, UV-vis and luminescence spectroscopy. The double-layer electroluminescence devices based on the Re (Ⅰ) complex have been fabricated by spin-coating technique. The turn-on voltage, maximum efficiency, and brightness for green emission obtained from the devices are 9 V, 2.1 cd/A and 165 cd/m2, respectively.
English
Synthesis,characterization,photoluminescence and electroluminescence properties of new 1,3,4-oxadiazole-containing rhenium (Ⅰ) complex Re (CO)3 (Bphen)(PTOP)
Abstract:
A new 1, 3, 4-oxadiazole-contanining rhenium (Ⅰ) complex, with the formula[Re (CO)3 (Bphen)(PTOP)], (Bphen=bathophenardine, PTOP=4-(5-p-tolyl-1, 3, 4-oxadiazd-2-yl) pyridine), is synthesized and characterized by elemental analysis, IR, 1H NMR, UV-vis and luminescence spectroscopy. The double-layer electroluminescence devices based on the Re (Ⅰ) complex have been fabricated by spin-coating technique. The turn-on voltage, maximum efficiency, and brightness for green emission obtained from the devices are 9 V, 2.1 cd/A and 165 cd/m2, respectively.
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Key words:
- Rhenium (Ⅰ) complex
- / Oxadizole-founctionalized
- / Electroluminescence
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